EXERCISE

The increasing order of the strength of hydrogen bond in the following mentioned linkages is:

(i) $\mathrm{O}-\mathrm{H}\cdots \mathrm{S}$

(ii) $\mathrm{S}-\mathrm{H}\cdots \mathrm{O}$

(iii) $\mathrm{F}-\mathrm{H}\cdots {\mathrm{F}}^{-}$

(iv) $\mathrm{F}-\mathrm{H}\cdots \mathrm{O}$

In the dichromate dianion:

${\mathrm{CH}}_3\mathrm{Cl}$ has more dipole moment than ${\mathrm{CH}}_3\mathrm{F}$ because:

Amongst ${\mathrm{NH}}_3, {\mathrm{PH}}_3, {\mathrm{AsH}}_3$ and ${\mathrm{SbH}}_3$, the one with the highest boiling point is:

Select the incorrect statement.

Consider the following statements.

${\mathrm{S}}_1$: The percentage of $\mathrm{s}-$character in the orbital forming $\mathrm{S}-\mathrm{S}$ bonds and $\mathrm{P}-\mathrm{P}$ bonds in ${\mathrm{S}}_8$ and ${\mathrm{P}}_4$ molecules, respectively, are the same.

${\mathrm{S}}_2$: In ${\mathrm{SF}}_4$, the bond angles, instead of being $90°$ and $180°$ are $89°$ and $177°$, respectively, due to the repulsions between lone pair and bond pairs of electrons.

${\mathrm{S}}_3$: Aqueous ${\mathrm{H}}_3{\mathrm{PO}}_4$ is syrupy (i.e., more viscous than water).

${\mathrm{S}}_4$: ${\mathrm{SiO}}_2$ crystal may be considered as a giant molecule in which, eight-membered rings are formed with alternate silicon and oxygen atoms.

Of these:

Which of the following is a wrong order with respect to the property mentioned against each?

Which of the following is correct?