Seema Saini Solutions for Chapter: Periodic Classification of Elements and General Inorganic Chemistry, Exercise 2: DPP

Author:Seema Saini

Seema Saini Chemistry Solutions for Exercise - Seema Saini Solutions for Chapter: Periodic Classification of Elements and General Inorganic Chemistry, Exercise 2: DPP

Attempt the practice questions on Chapter 1: Periodic Classification of Elements and General Inorganic Chemistry, Exercise 2: DPP with hints and solutions to strengthen your understanding. Chapterwise/Topicwise Daily Practice Problems (DPP) Inorganic Chemistry Part - 1 JEE Main & Advanced solutions are prepared by Experienced Embibe Experts.

Questions from Seema Saini Solutions for Chapter: Periodic Classification of Elements and General Inorganic Chemistry, Exercise 2: DPP with Hints & Solutions

MEDIUM
JEE Advanced
IMPORTANT

I2 is a crystalline solid. It is a molecular solid in which I2 molecules are held together with van der Waals forces. Given diagram represents two adjacent I2 molecules in I2 solid.

Question Image

If A-C length =6.96 Ao and covalent radius of iodine is =1.33 Ao

 

Find the Van der Waals radius of I atom.

EASY
JEE Advanced
IMPORTANT

I2 is a crystalline solid. It is a molecular solid in which I2 molecules are held together with van der Waals forces. Given diagram represents two adjacent I2 molecules in I2 solid.

Question Image

If A-C length =6.96 Ao and covalent radius of iodine is =1.33 Ao  

Which of the following data is smaller as compared to 1.33 Ao?

HARD
JEE Advanced
IMPORTANT

According to I. C. Slater effective nuclear charge, Z*, due to screening, is not exactly equal to the actual nuclear charge Z of the nucleus of the atom. Z* depends on the type of orbital In which the electron is housed, and on the ability of other electrons
in more penetrating orbitals to screen the electron in question from the nucleus.
The relative extent to which the various orbitals penetrate the electron clouds of other orbitals is s>p>d>f. The effective nuclear charge Z* due to screening is given by Z*=Z-σ where Z is the atomic number and σ is the slater screening constant values:0<σ<Z

Electrons
in orbitals
σ per electron in orbital
n n-1 (n-2), (n-3), etc.
s or p orbital 0.35 0.85 1.00
d or forbital 0.35 1.00 1.00

Screening effect of one electron in the outermost orbital, is not considered in calculation of σ.

What is the value of Z* for Rb (37)?

HARD
JEE Advanced
IMPORTANT

According to I. C. Slater effective nuclear charge, Z*, due to screening, is not exactly equal to the actual nuclear charge Z of the nucleus of the atom. Z* depends on the type of orbital In which the electron is housed, and on the ability of other electrons
in more penetrating orbitals to screen the electron in question from the nucleus.
The relative extent to which the various orbitals penetrate the electron clouds of other orbitals is s>p>d>f. The effective nuclear charge Z* due to screening is given by Z*=Z-σ where Z is the atomic number and σ is the slater screening constant values:0<σ<Z

Electrons
in orbitals
σ per electron in orbital
n n-1 (n-2), (n-3), etc.
s or p orbital 0.35 0.85 1.00
d or forbital 0.35 1.00 1.00

Screening effect of one electron in the outermost orbital, is not considered in calculation of σ.

What is Z* for Cu(29)?

HARD
JEE Advanced
IMPORTANT

According to I. C. Slater effective nuclear charge, Z*, due to screening, is not exactly equal to the actual nuclear charge Z of the nucleus of the atom. Z* depends on the type of orbital In which the electron is housed, and on the ability of other electrons
in more penetrating orbitals to screen the electron in question from the nucleus.
The relative extent to which the various orbitals penetrate the electron clouds of other orbitals is s>p>d>f. The effective nuclear charge Z* due to screening is given by Z*=Z-σ where Z is the atomic number and σ is the slater screening constant values:0<σ<Z

Electrons
in orbitals
σ per electron in orbital
n n-1 (n-2), (n-3), etc.
s or p orbital 0.35 0.85 1.00
d or forbital 0.35 1.00 1.00

Screening effect of one electron in the outermost orbital, is not considered in calculation of σ.

In which of the following cases the concept of Z* is applicable?