JEE Main - 8th April 2017

In the above conversion of compound ($\mathrm{X}$) to product ($\mathrm{Y}$), the sequence of reagents to be used will be:

How many of the transformation given below would result in aromatic amines?

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): $\alpha$-halocarboxylic acid on reaction with dil. ${\mathrm{NH}}_3$ gives good yield of $\alpha$-amino carboxylic acid whereas the yield of amines is very low when prepared from alkyl halides.

Reason (R): Amino acids exist in zwitter ion form in aqueous medium.

In the light of the above statements, choose the correct answer from the options given below :

Benzyl isocyanide can be obtained by:

(A)
 

(B)
 

(C)
 

(D)
 

Choose the correct answer from the options given below:

Cyclohexylamine when treated with nitrous acid yields (P). On treating (P) with PCC results in (Q). When (Q) is heated with dil. $\mathrm{NaOH}$ we get (R) The final product (R) is:

An organic compound $\left[\mathrm{A}\right]\left({\mathrm{C}}_4{\mathrm{H}}_{11} \mathrm{N}\right)$, shows optical activity and gives ${\mathrm{N}}_2$ gas on treatment with ${\mathrm{HNO}}_2$. The compound $\left[\mathrm{A}\right]$ reacts with ${\mathrm{PhSO}}_2\mathrm{Cl}$ producing a compound which is soluble in $\mathrm{KOH}$. The structure of $\mathrm{A}$ is :

In the following reaction, ‘$\mathrm{A}$’ is