Embibe Experts Solutions for Chapter: Organic Compounds with Functional Groups Containing Nitrogen, Exercise 1: Exercise 1

${\mathrm{CH}}_3{\mathrm{NO}}_2\underset{\mathrm{HCl}}{\overset{{\mathrm{SnCl}}_2}{\to }}{\mathrm{CH}}_3\mathrm{X}$, the ${}^{\text{'}}\mathrm{X}^{\text{'}}$ contains

Which of the following statement is not correct regarding aniline?

When ethylamine reacts with sodium metal, the gas evolved is:

Treatment of ammonia with an excess of ethyl iodide will yield

${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Cl}\stackrel{\mathrm{NaCN}}{⟶}\mathrm{X}\stackrel{\mathrm{Ni}/{\mathrm{H}}_2}{⟶}\mathrm{Y}$$\stackrel{\mathrm{acetic} \mathrm{anhydride} }{\to }$$\mathrm{Z}$

$\mathrm{Z}$ in the above reacting sequence is

Aniline reacts with phosgene and $\mathrm{KOH}$ to form:

Aniline when treated with concentrated ${\mathrm{HNO}}_3$, gives

The minor product formed when aniline is heated with concentrated ${\mathrm{HNO}}_3+$concentrated ${\mathrm{H}}_2{\mathrm{SO}}_4$  at $288\mathrm{K}$: