HARD
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2-Methyl propyl bromide reacts with C2H5O-and gives A whereas on reaction with C2H5OH it gives B. The mechanism followed in these reactions and the products A and B respectively are:

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Important Questions on Halogen Derivatives

HARD
Allyl phenyl ether can be prepared by heating :
MEDIUM
The order of SN1 reactivity in aqueous acetic acid solution for the compounds
(1) H 3 C - C || O - C H 2 - C l

(2) H3C-CH2-CH2-Cl

(3) H3C3C-Cl

is
HARD

The major product of the following reaction is:

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MEDIUM

The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is:

(i) Question Image

(ii)  Question Image

(iii) Question Image

(iv) Question Image

HARD

For the following compounds the correct statement(s) with respect to nucleophilic substitution reactions is(are)

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EASY
Which of the following, upon treatment with tert-BuONa  followed by addition of bromine water, fails to decolourize the colour of bromine?
HARD
The major products A and B for the following reactions are, respectively:
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EASY
Consider the reaction
CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr
This reaction will be the fastest in
EASY

The reagent required for the following two step transformation are

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MEDIUM
Increasing order of reactivity of the following compounds for SN1 substitution is:
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MEDIUM
In SN2 reactions, the correct order of reactivity for the following compounds :
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is :
MEDIUM
Increasing rate of SN1 reaction in the following compounds is:
(I)Question Image
(II) Question Image
(III)Question Image
(IV) Question Image
MEDIUM
In a nucleophilic substitution reaction :  R - Br + Cl - DMF R - Cl + Br - ,  which one of the following undergoes complete inversion of configuration ?
MEDIUM
The major product of the following reaction is:
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MEDIUM
An ‘Assertion’ and a ‘Reason’ is given below. Choose the correct answer from the following options:
Assertion A: Vinyl halides do not undergo nucleophilic substitution easily.
Reason R: Even though the intermediate carbocation is stabilized by loosely held π- electrons, the cleavage is difficult because of the strong bonding.
MEDIUM
Which of the following potential energy (P.E.) diagrams represents the SN1 reaction?
EASY
The increasing order of the reactivity of the following halides for the SN1 reaction is

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MEDIUM
How do you distinguish chlorobenzene from benzyl chloride?
MEDIUM
Compound (A), C8H9Cl, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (A) gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).