EASY
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At moderate pressure, the compressibility factor of a particular gas is given by Z=1+0.34p-170pT  (p in bar and T in Kelvin) 

What is the Boyle's temperature of this gas?

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Important Questions on States of Matter

HARD

A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3 mol-1 at a temperature of 800 K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  y dm3 mol-1 . The value of x/y is _________

[Use: Gas constant, R=8×10-2 L atm K-1 mol-1 ]

EASY
In the following compressibility factor (Z) vs pressure graph at 300 K, the compressibility of CH4 at pressure < 200 bar deviates from ideal behavior because

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MEDIUM

Among the gases a, b, c, d, e and f, the gases that show only positive deviation from ideal behavior at all pressures in the graph are

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EASY
Among the following, the incorrect statement is:
MEDIUM
Which of the following gases has high Boyle's temperature?
MEDIUM
When does a gas deviate the most from its ideal behavior?
EASY
The compressibility factor (Z) of a gas is <1 at STP. Therefore
HARD
Van der Waal's equation for a gas is stated as,

P=nRTV-nb-anV2.

This equation reduces to the perfect gas equation, P=nRTV When,
EASY
For an ideal gas, the compressibility factor is
HARD

The isotherms of a gas are shown below :

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Among the following,

(i) At T1, the gas cannot be liquefied

(ii) At point B, liquid starts to appear at T2

(ii) TC is the highest temperature at which the gas can be liquefied

(iv) At point A, a small increase in pressure condenses the whole system to a liquid

The correct statements are :

MEDIUM

The variation of the compressibility factor (Z) with pressure (P in bar) for some gases, are shown in the figure below. Identify the gases (A),(B) and (C).

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MEDIUM
A gas at 350 K and 15 bar has a molar volume 20 per cent smaller than that for an ideal gas under the same conditions. The correct option about the gas, and its compressibility factor Z is
HARD
Which one of the following plots is correct for the behaviour of ideal and real gases?
EASY
A gas such as carbon monoxide would be most likely to obey the ideal gas law at:
MEDIUM
The pressure p and volume V isotherm of a van der Waals' gas, at the temperature at which it undergoes gas to liquid transition, is correctly represented by
EASY
At very high pressures, the compressibility factor of one mole of a gas is given by:
HARD
One mole of a monoatomic real gas satisfied the equation pV-b=RT where b is a constant. The relationship of interatomic potential V(r) and interatomic distance r for the gas is given by
EASY
A certain gas obeys PVm-b=RT. The value of ZPT is xbRT. The value of x is              (Integer answer) (Z : compressibility factor)
HARD
For one mole of a van der Waals' gas, the compressibility factor Z=pVRT at a fixed volume will certainly decrease, if
[Given : " a " and " b " are standard parameters for van der Waals' gas]
 
HARD
If Z is the compressibility factor, then Van der Waal's equation at low pressure can be written as: