HARD
JEE Main
IMPORTANT
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Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

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Important Questions on Electrochemistry

EASY
JEE Main
IMPORTANT

Which one of the following statements is correct for electrolysis of brine solution?

MEDIUM
JEE Main
IMPORTANT

The logarithm of equilibrium constant for the reaction Pd2++4Cl-PdCl42-   is
(Nearest integer)

Given: 2.303RTF=0.06 V

Pd(aq)2++2e-Pd(s)  Eo=0.83 V

PdCl42-(aq)+2e-Pd(s)+4Cl-(aq)

Eo=0.65 V

MEDIUM
JEE Main
IMPORTANT
The resistivity of a 0.8M solution of an electrolyte is 5×10-3Ωcm. Its molar conductivity is 104Ω-1 cm2 mol-1. (Nearest integer)
HARD
JEE Main
IMPORTANT

1×10-5 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this solution at 298 K is _______×10-8 S m-1.

[Given : Ksp(AgBr)=4.9×10-13 at 298 K

λAg+0=6×10-3Sm2 mol-1

λBr-0=8×10-3Sm2 mol-1

λNO3-0=7×10-3Sm2 mol-1

EASY
JEE Main
IMPORTANT
Amongst the following, the form of water with the lowest ionic conductance at 298K is:
MEDIUM
JEE Main
IMPORTANT
To find the standard potential of M3+/M electrode, the following cell is constituted: Pt/M/M3+ 0.001 mol L-1/Ag+ 0.01 mol L-1/Ag

The emf of the cell is found to be 0.421 volt at 298 K. The standard potential of half-reaction M3++3e-M at 298 K will be:

(Given: EAg+Ag at 298 K=0.80 volt)
HARD
JEE Main
IMPORTANT
For an electrochemical cell SnsSn2+aq,1MPb2+aq,1MPbs the ratio Sn2+Pb2+ when this cell attains equilibrium is _______.
(Given: ESn2+Sn0=-0.14V,EPb2+Pb0=-0.13V,  2.303RTF=0.06 log2.15 = 13)
HARD
JEE Main
IMPORTANT
What would be the electrode potential for the given half-cell reaction at pH=5?
2H2OO2+4H+4e-;Ered0=1.23V
R=8.314 Jmol-1K-1;Temp=298K; oxygen under standard atm. pressure of 1bar