HARD
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Choose the halogen which is most reactive towards SN1 reaction in the given compounds (A, B, C & D)

A. Question Image

B. Question Image

C. Question Image

D. Question Image

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Important Questions on Organic Compounds Containing Halogens

EASY
Which of the following, upon treatment with tert-BuONa  followed by addition of bromine water, fails to decolourize the colour of bromine?
EASY

In the following passage there are blanks, each of which has been numbered. There are questions given below the passage and for each question, four words are suggested, one of which fits the blank appropriately. Find out the appropriate word in each case.

Whenever I go into a bank, I feel scared. Everybody and everything that I see there (1) ____ me. As for the manager the sight (2) ____ him simply terrifies me and (3) ____ me want to runaway (4) _____ I can. As soon as I (5) ____ the door of the bank I lose my head (6) ____ when I try to do any (7) ____ there, I behave like an idiot. I cannot explain (8) ____ for this but that is how it (9) ____ has been that is how it is (10) ____.

Select the most appropriate option for blank No. 10.

EASY
The increasing order of the reactivity of the following halides for the SN1 reaction is

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MEDIUM
In a nucleophilic substitution reaction :  R - Br + Cl - DMF R - Cl + Br - ,  which one of the following undergoes complete inversion of configuration ?
MEDIUM
Compound (A), C8H9Cl, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (A) gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).
EASY

The reagent required for the following two step transformation are

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MEDIUM
In SN2 reactions, the correct order of reactivity for the following compounds :
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is :
MEDIUM
How do you distinguish chlorobenzene from benzyl chloride?
HARD

For the following compounds the correct statement(s) with respect to nucleophilic substitution reactions is(are)

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MEDIUM
The order of SN1 reactivity in aqueous acetic acid solution for the compounds
(1) H 3 C - C || O - C H 2 - C l

(2) H3C-CH2-CH2-Cl

(3) H3C3C-Cl

is
MEDIUM
Increasing rate of SN1 reaction in the following compounds is:
(I)Question Image
(II) Question Image
(III)Question Image
(IV) Question Image
HARD
The major products A and B for the following reactions are, respectively:
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MEDIUM
Increasing order of reactivity of the following compounds for SN1 substitution is:
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EASY
Consider the reaction
CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr
This reaction will be the fastest in
MEDIUM

The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is:

(i) Question Image

(ii)  Question Image

(iii) Question Image

(iv) Question Image

MEDIUM

In the reaction given below what will be the major product at the end :

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