MEDIUM
JEE Main
IMPORTANT
Earn 100

Decarboxylation of all six possible forms of diaminobenzoic acids C6H3NH22COOH yields three products A,B and C. Three acids give a product 'A', two acids gives a product 'B' and one acid give a product 'C'. The melting point of product 'C' is

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Important Questions on Amines

MEDIUM
JEE Main
IMPORTANT

Identify the major product formed in the following sequence of reactions :

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MEDIUM
JEE Main
IMPORTANT
In Friedel-Crafts alkylation of aniline, one gets:
MEDIUM
JEE Main
IMPORTANT
An organic compound 'A' on reaction with NH3 followed by heating gives compound B. Which on further strong heating gives compound C C8H5NO2. Compound C on sequential reaction with ethanolic KOH, alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A is
MEDIUM
JEE Main
IMPORTANT

The correct stability order of the following diazonium salt is

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HARD
JEE Main
IMPORTANT

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Experimental reaction of CH3Cl with aniline and anhydrous AlCl3 does not give o and p-methylaniline.

Reason R : The -NH2 group of aniline becomes deactivating because of salt formation with anhydrous AlCl3 and hence yields m-methyl aniline as the product.

In the light of the above statements, choose the most appropriate answer from the options given below

HARD
JEE Main
IMPORTANT

The correct sequential order of the reagents for the given reaction is

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MEDIUM
JEE Main
IMPORTANT

Match List-I with List-II

  List-I   List-II
A Benzenesulphonyl chloride I Test for primary amines
B Hoffmann bromamide reaction II Anti Saytzeff
C Carbylamine reaction III Hinsberg reagent
D Hoffmann orientation IV

Known reaction of Isocyanates.

Choose the correct answer from the options given below

HARD
JEE Main
IMPORTANT
An organic compound 'A' contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound 'A' with standard base indicates that the molecular weight of 'A' is 131±2. When a sample of 'A' is treated with aq. NaOH, a liquid separates which contains N but not Cl. Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound 'A' is