HARD
JEE Main / Advanced
IMPORTANT
Earn 100

Draw the Carnot cycle for a monatomic gas on the log-log scale using the pT - and VT-coordinates.

Important Questions on Molecular Physics and Thermodynamics

HARD
JEE Main / Advanced
IMPORTANT

A gas is transferred from an initial state 0 to other states 1, 2, 3, and 4 via different isoprocesses. Which curve representing the dependence of entropy on temperature corresponds to which process?

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HARD
JEE Main / Advanced
IMPORTANT
Draw the Carnot cycle in the ST-coordinates.
HARD
JEE Main / Advanced
IMPORTANT
Two objects with initial temperatures T1 and T2 (with T1>T2) are brought into contact. The objects are isolated from their surroundings, and the masses and heat capacities of the two objects are equal. How does the total entropy of these objects change as the temperatures become equal?
MEDIUM
JEE Main / Advanced
IMPORTANT

Suppose that the entropy grows linearly with temperature in a process. How does the heat capacity vary with temperature?

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HARD
JEE Main / Advanced
IMPORTANT

A gas is transferred from a state 1 to a state 2 in two ways: (a) directly by an isobar, and (2) first by the isochor 1-3; then by the isobar 3-4, and, finally, by the isochor 4-2. Show, by direct calculation, that the entropy increment in both cases is the same.

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HARD
JEE Main / Advanced
IMPORTANT
A heat engine operates according to a cycle that consists of two isochors and two isobars. Prove that the entropy of the heater-gas-cooler system increases as the engine operates. How does the entropy of the gas change in the process? The heat capacities of the heater and cooler are assumed to be infinite.
HARD
JEE Main / Advanced
IMPORTANT

According to the van der Waals equation, which is a third-degree equation in the volume, the theoretical isotherm of a real gas may have either one or three intersections with a horizontal line, the intersections corresponding to either one or three real roots of the equation. With three roots it may so happen that two are equal (maxima and minima on the isotherm) or even all three are equal (the critical point). However, on an isotherm built for a sufficiently low temperature there is a section lying below the horizontal axis, and a horizontal line in this case intersects the section only at two points (two roots in V). Where in this case is the compulsory third root?

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MEDIUM
JEE Main / Advanced
IMPORTANT

The section 1-3 on the theoretical isotherm of a real gas (the van der Waals isotherm) is assumed to be unrealistic because of its absolute instability. What is the reason for this instability?

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