Explain the terms: Homolytic and heterolytic cleavage

Name the type of isomers the following pair represents (with justification).

${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CHO} \mathrm{and} {\mathrm{CH}}_3{\mathrm{COCH}}_3$

Name the type of isomers the following pair represents (with justification).

${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2\mathrm{CHO} \mathrm{and} {\mathrm{CH}}_3\mathrm{CH}\left(\mathrm{CHO}\right){\mathrm{CH}}_3$

Name the type of isomers the following pair represents (with justification).

${\mathrm{CH}}_3-\mathrm{CH}=\mathrm{CH}-{\mathrm{CH}}_3 \mathrm{and} {\mathrm{CH}}_2=\mathrm{CH}-{\mathrm{CH}}_2-{\mathrm{CH}}_3$

Name the type of isomers the following pair represents (with justification).

${\mathrm{CH}}_3-{\mathrm{CH}}_2-\mathrm{NH}-{\mathrm{CH}}_2-{\mathrm{CH}}_3 \mathrm{and} {\mathrm{CH}}_3{\mathrm{NHCH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$

Name the type of isomers the following pair represents (with justification).

${\mathrm{CH}}_3-\mathrm{CHO} \mathrm{and} {\mathrm{CH}}_2=\mathrm{CHOH}$