MEDIUM
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For a ___________________ internal energy of a system does not remain constant.

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Important Questions on Thermodynamics

EASY
Which of the following does not follow first law of thermodynamics? (w=work ;q= heat ;ΔU= change in internal energy )
MEDIUM

One mole of an ideal diatomic gas undergoes a transition from A to B along a path AB as shown in figure. The change in internal energy of the gas during the transition is

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MEDIUM

The P-V diagram shown below indicates two paths along which a sample of gas can be taken from state A to state B. The energy equal to 5 PV in the form of heat is required to be transferred if the Path-1 is chosen. How much energy in the form of heat should be transferred if Path-2 is chosen?

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MEDIUM

A gas undergoes a thermodynamic cycle as shown in pressure-volume diagram below. The heat transferred to the gas is 300 J and 140 J along path 12 and 23 respectively. The internal energy is changed by -260 J along path 31. The work done by gas along path 123 is

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HARD

The equation of state of nmoles of a non-ideal gas can be approximated by the equation p+n2aV2(V-nb)=nRT where, a and, b are constant characteristics of the gas. Which of the following can represent the equation of a quasi-static adiabatic for this gas (assume that, CV is the molar heat capacity at constant volume is independent of temperature)?

MEDIUM
The internal energy of the air, in a room of volume V, at temperature T and with outside pressure P increasing linearly with time, varies as
EASY
The first law of thermodynamics confirms the law of _____
MEDIUM
The amount of heat needed to raise the temperature of 4 moles of a rigid diatomic gas from 0 °C to 50 °C when no work is done is (R is the universal gas constant)
HARD
An ideal gas is undergoing a cyclic thermodynamic process in different ways as shown in the corresponding P-V diagrams in column 3 of the table. Consider only the path from state 1 to state 2. W denotes the corresponding work done on the system. The equations and plots in the table have standard notations as used in thermodynamic process. Here γ is the ratio of heat capacities at constant pressure and constant volume. The number of moles in the gas is n.
 
Column – 1 Column – 2 Column – 3
(I) W12=1γ-1P2V2-P1V1 (i) Isothermal (P) Question Image
(II) W12= -PV2+PV1 (ii) Isochoric (Q) Question Image
(III) W12=0 (iii) Isobaric (R) Question Image
(IV) W12= -nRTlnV2V1 (iv) Adiabatic (S) Question Image
Which of the following options is the only correct representation of the process U=Q-PV ?
MEDIUM
A sample of an ideal gas is taken through the cyclic process abca as shown in the figure. The change in the internal energy of the gas along the path ca is -180 J. The gas absorbs 250 J of heat along the path ab and 60 J along the path bc . The work done by the gas along the path abc is:
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MEDIUM

An ideal gas is made to undergo the cyclic process shown in the figure below.
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Let ΔW depict the work done, ΔU be the change in internal energy of the gas and Q be the heat added to the gas. Sign of each of these three quantities for the whole cycle will be (0 refers to no change)

MEDIUM
In a thermodynamic system, Q represents the energy transferred to or from a system by heat and W represents the energy transferred to or from a system by work

(I) Q>0 and W=0

(II) Q<0 and W=0

(III) W>0 and Q=0

(IV) W<0 and Q=0

Which of the above will lead to an increase in the internal energy of the system?
HARD
Certain quantity of heat is supplied to a monatomic ideal gas which expands at constant pressure. The percentage of heat that is used to do work by the gas is
EASY

A given quantity of gas is taken from the state A to the state C reversibly by two paths, AC directly and A BC as shown in the figure below:

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During the process AC, work done by the gas is 100 J and heat absorbed is 120 J. If during the process ABC, the work done by the gas is 80 J, the heat absorbed is

EASY
When 110 J of heat is added to a gaseous system, its internal energy increases by 40 J. What is the amount of work done?
EASY
No work is done on the system, but q amount of heat is taken out from the system and given to the surroundings. Express the change in internal energy (ΔU) of this system and what type of wall does the system have?
EASY

When a system is taken from state i to state f along the path iaf, it is found that Q=50 cal and W=20 calAlong the path ibfQ'=36 calW along the path ibf is,

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EASY
Five moles of an ideal monoatomic gas with an initial temperature of 150 °C expand and in the process absorb 1500 J of heat and does 2500 J of work. The final temperature of the gas in °C is (ideal gas constant, R=8.314 J K-1 mol-1 ). 
EASY
Figure below shows two paths that may be taken by a gas to go from a state A to a state C.
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In process AB, 400 J of heat is added to the system and in process BC, 100 J of heat is added to the system. The heat absorbed by the system in the process AC will be: