HARD
JEE Advanced
IMPORTANT
Earn 100

For the following reaction the rate of reaction is . Two moles of are mixed with one mole of to make of solution. At mole of is left in the reaction mixture. The correct statement(s) about the reaction is(are) Use:
(a)The rate constant, , of the reaction is .
(b)Half-life of is .
(c)At .
(d)At

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Important Questions on Chemical Kinetics
HARD
JEE Advanced
IMPORTANT
Which of the following plots is(are) correct for the given reaction?
( is the initial concentration of )

HARD
JEE Advanced
IMPORTANT
The decomposition reaction is started in a closed cylinder under the isothermal isochoric condition at an initial pressure of . After , the pressure inside the cylinder is found to be . If the rate constant of the reaction is , assuming ideal gas behaviour, the value of is(nearest integer)

HARD
JEE Advanced
IMPORTANT
For a first order reaction at constant volume and 300 K, the total pressure at the beginning and at time are , respectively. Initially, only A is present with concentration , and is the time required for the partial pressure of A to reach of its initial value. The correct option(s) is (are)
(Assume that all these gases behave as ideal gases)

HARD
JEE Advanced
IMPORTANT
Consider the following reversible reaction:
The activation energy of the backward reaction exceeds that of the forward reaction by (in ). If the pre-exponential factor of the forward reaction is times that of the reverse reaction, the absolute value of for the reaction at is ____.
(Given; and is the Gibbs energy)

HARD
JEE Advanced
IMPORTANT
In a bimolecular reaction, the steric factor was experimentally determined to be . The correct option(s) among the following is(are)

EASY
JEE Advanced
IMPORTANT
For the elementary reaction , the rate of disappearance of increases by a factor of upon doubling the concentration of . The order of the reaction with respect to is

HARD
JEE Advanced
IMPORTANT
is known to undergo radioactive decay to form by emitting alpha and beta particles. A rock initially contained of . If the number of alpha particles that it would emit during its radioactive decay of to in three half-lives is , then what is the value of ?

HARD
JEE Advanced
IMPORTANT
Consider the kinetic data given in the following table for the reaction Product.
Experiment No. | Rate of reaction | |||
The rate of the reaction for and is found to be The value of is __________
