HARD
JEE Advanced
IMPORTANT
Earn 100

For the following reaction 2X+YkP the rate of reaction is d[P]dt=k[X]. Two moles of X are mixed with one mole of Y to make 1.0 L of solution. At 50 s, 0.5 mole of Y is left in the reaction mixture. The correct statement(s) about the reaction is(are) (Use: ln 2=0.693)

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Important Questions on Chemical Kinetics

HARD
JEE Advanced
IMPORTANT

Which of the following plots is(are) correct for the given reaction?

([P]0 is the initial concentration of P)

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HARD
JEE Advanced
IMPORTANT

The decomposition reaction 2N2O5g  2N2O4g+O2g is started in a closed cylinder under the isothermal isochoric condition at an initial pressure of 1 atm. After Y10×103 s , the pressure inside the cylinder is found to be 1.45 atm . If the rate constant of the reaction is 5×10-4s-1, assuming ideal gas behaviour, the value of Y is(nearest integer)

HARD
JEE Advanced
IMPORTANT
For a first order reaction A(g)  2B(g) + C(g) at constant volume and 300 K, the total pressure at the beginning (t = 0) and at time are  p0 and pt, respectively. Initially, only A is present with concentration  A0, and  t13  is the time required for the partial pressure of A to reach 1/3rd of its initial value. The correct option(s) is (are)
(Assume that all these gases behave as ideal gases)
HARD
JEE Advanced
IMPORTANT
Consider the following reversible reaction:

A g+B gAB g

The activation energy of the backward reaction exceeds that of the forward reaction by 2RT (in  mol-1). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction, the absolute value of G  (in J mol-1) for the reaction at 300 K is ____.

(Given; ln2= 0.7,  = 2500 J mol-1 at 300 K and G is the Gibbs energy)
HARD
JEE Advanced
IMPORTANT
In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among the following is(are)
EASY
JEE Advanced
IMPORTANT
For the elementary reaction MN, the rate of disappearance of M increases by a factor of 8 upon doubling the concentration of M. The order of the reaction with respect to M is
HARD
JEE Advanced
IMPORTANT
U92238 is known to undergo radioactive decay to form Pb82206 by emitting alpha and beta particles. A rock initially contained 68×10-6g of U92238. If the number of alpha particles that it would emit during its radioactive decay of U92238 to Pb82206 in three half-lives is Z×1018, then what is the value of Z?
HARD
JEE Advanced
IMPORTANT
Consider the kinetic data given in the following table for the reaction A+B+C Product.
 
Experiment No. A mol dm-3 B mol dm-3 C mol dm-3 Rate of reaction mol dm-3s-1
1 0.2 0.1 0.1 6.0×10-5
2 0.2 0.2 0.1 6.0×10-5
3 0.2 0.1 0.2 1.2×10-4
4 0.3 0.1 0.1 9.0×10-5


The rate of the reaction for A=0.15 mol dm-3, B=0.25 mol dm-3 and C=0.15 mol dm-3 is found to be Y×10-5 mol dm-3s-1. The value of Y is __________