EASY

Earn 100

Give an example for a first order reaction.

Important Questions on Chemical Kinetics

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

It takes

1 h

for a first order reaction to go to

50 %

completion. The total time required for the same reaction to reach

87.5 %

completion will be

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

One gram of (

A

) decays by

β

-emission to

0.125 g

200

years. The half-life period of the reaction is

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

aP + bQ \to Products

, when

[P]

is doubled keeping

|Q|

constant rate increases

2

times, when

[P]

is constant and

|Q|

is doubled, rate increases four times. The overall order is

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

What are elementary reactions?

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

The reaction

2 NO (g) + O_{2} (g) \to 2 {NO}_{2} (g)

is of the first-order. If the volume of the reaction vessel is reduced to

1 / 3,

the rate of the reaction would be

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

A first order reaction takes

40

minutes for

30 %

completion. Calculate the half life of reaction.

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

In a chemical reaction

A + 2 B \to

products, when concentration of

A

is doubled, rate of the reaction increases

4

times and when concentration of

B

alone is doubled rate continues to be the same. The order of the reactions is

MEDIUM

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

The rate of a reaction is found to depend upon two concentration variables. What should be the order of the reaction?

MEDIUM

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

For the chemical reaction

$2 O_{3} ⟶ 3 O_{2}$ , the reaction proceeds as follows

$O_{3} ⇌ O_{2} + O$ (Fast)

$O + O_{3} ⟶ 2 O_{2}$ , (Slow)

the rate law expression should be given as

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

The rate constant is same for

3

reactions of order

I

II

and

III

, respectively, the unit of concentration being in moles per litre. If the concentration of the reactant is unity, the rates of reaction

R_{1}, R_{2}, R_{3}

will be

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

The units for the rate constant and the rate of reaction are same for a reaction. What will be the order of the reaction?

MEDIUM

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

Decomposition of

H_{2} O_{2}

follows a first order reaction. In fifty minutes the concentration of

H_{2} O_{2}

decreases from

0.5

0.125 M

in one such decomposition. When the concentration of

H_{2} O_{2}

reaches

0.05 M

, the rate of formation of

O_{2}

will be:

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

Hydrolysis of ester is a first order reaction. For this reaction, the correct statement is

HARD

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

Gaseous cyclobutene isomerizes to butadiene in a first order process which has a '

K

' value of

3.3 \times 10^{- 4} s^{- 1}

153 ° C .

The time in minutes it takes for the isomerization to proceed

40 %

to completion at this temperature is_____. (Rounded off to the nearest integer)

HARD

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

What will be the order of the reaction for hydrolysis of methyl acetate with $NaOH$ by using the data provided?

Time $(\min) 0 5 10 15$
Volume of acid $(mL) 10.12 6.24 1.40 0.981$

MEDIUM

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

Graph plotted between

\log t_{1 / 2}

versus log concentration

(a)

is a straight line. What conclusion can you draw from the graph?

Question Image

$n =$ order of reaction

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

For a certain reaction between

X

and

Y,

the order with respect to

X

3

and that with respect to

Y

4 .

If the concentrations of both

X

and

Y

are tripled. the rate of reaction will increase by a factor of ________

MEDIUM

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

The time required for

60 %

completion of a first order reaction is

50 \min

. The time required for

93.6 %

completion of the same reaction will be

EASY

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

For the elementary reaction

M \to N

, the rate of disappearance of

M

increases by a factor of

8

upon doubling the concentration of

M

. The order of the reaction with respect to

M

HARD

Chemistry>Physical Chemistry>Chemical Kinetics>Integrated Rate Law for Zero and First Order Reactions

In the reaction,

P + Q \to R + S

the time taken for

75 %

reaction of

P

is twice the time taken for

50 %

reaction of

P

. The concentration of

Q

varies with reaction time as shown in the figure.The overall order of the reaction is:

Question Image

Give an example for a first order reaction.

Important Questions on Chemical Kinetics

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