HARD
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How will you convert aniline into phenyl isocyanide?

Important Questions on Amines

MEDIUM
Aniline reacts with excess Br2/H2O to give the major product
MEDIUM
The amine which reacts with p-toluene sulphonyl chloride to give a clear solution which on acidification gives insoluble compound is
EASY
Describe a method for the identification of primary, secondary and tertiary amines. Also, write chemical equations of the reactions involved.
MEDIUM
On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is :
MEDIUM
The following reaction

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Is known by the name:
EASY

In the reaction sequence
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X and Y are, respectively,

EASY
The nitrosation of N,N-dimethylaniline takes place through the attack of electrophile:
HARD
The major product in the following reaction is:
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MEDIUM
A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass 390. The number of amino groups presents per molecule of the former compound is
EASY
Which one of the following nitro-compounds does not react with nitrous acid?
HARD

The major product obtained in the following reaction is:
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MEDIUM

The major product formed in the reaction given below will be :

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HARD
The final product formed when methylamine is treated with NaNO 2 and HCl followed by hydrolysis is:
HARD
The compound  X C7H9N reacts with benzenesulfonyl chloride to give  Y C13H13NO2S which is insoluble in alkali. The compound X is
MEDIUM
The test to distinguish primary, secondary and tertiary amines is:
HARD
Aniline dissolved in dilute HCl is reacted with sodium nitrite at 0°C. This solution was added dropwise to a solution containing an equimolar mixture of aniline and phenol in dilute HCl. The structure of the major product is
MEDIUM

Scheme 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3 describes the synthesis of T from Q and S. The total number of Br atoms in a molecule of T is

Scheme 1:

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Scheme 2:

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Scheme 3:

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EASY
Which of the following compounds will form significant amount of meta product during mono-nitration reaction?
HARD

The major product of the following reaction is:

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MEDIUM

What will be the major product in the following mononitration reaction?

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