MEDIUM
JEE Main
IMPORTANT
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In the following reaction; xAyB

log10-dAdt=log10-dBdt+0.3010

‘A’ and ‘B’ respectively can be:

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Important Questions on Chemical Kinetics

HARD
JEE Main
IMPORTANT

For an elementary chemical reaction, A2 k-1k12A , the expression for dAdt is:

HARD
JEE Main
IMPORTANT

Consider the given plots for a reaction obeying Arrhenius equation (0°C<T<300°C): ( K and Ea are rate constant and activation energy, respectively )

(I) 

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(II) 

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MEDIUM
JEE Main
IMPORTANT
For the reaction of H2 with I2, the rate constant is 2.5×10-4 dm3mol-1s-1 at 327oC and 1.0 dm3 mol-1s-1 at 527°C . The activation energy for the reaction, in kJ mol-1 is:

R=8.314 JK-1mol-1
MEDIUM
JEE Main
IMPORTANT
A bacterial infection in an internal wound grows as N't=N0exp(t) , where the time t is in hours. A dose of antibiotic, taken orally, needs 1 hour to reach the wound. Once it reaches there, the bacterial population goes down as dNdt=-5N2 . What will be the plot of N0N vs t after 1 hour?
MEDIUM
JEE Main
IMPORTANT

For a first order reaction, the time required for completion of 90% reaction is 'x' times the half life of the reaction. The value of 'x' is

(Given: ln10=2.303 and log2=0.3010)

HARD
JEE Main
IMPORTANT
For a given chemical reaction γ1A+γ2Bγ3C+γ4D. Concentration of C changes from 10 mmol dm-3 to 20 mmol dm-3 in 10 s. Rate of appearance of D is 1.5 times the rate of disappearance of B which is twice the rate of disappearance A. The rate of appearance of D has been experimentally determined to be 9 mmol dm-3s-1. Therefore the rate of reaction is____mmol dm-3s-1. (Nearest Integer)
MEDIUM
JEE Main
IMPORTANT
Catalyst A reduces the activation energy for a reaction by 10 kJ mol-1 at 300 K. The ratio of rate constants, kCatalysedk Uncatalysed is ex. The value of x is____[nearest integer] [Assume that the pre-exponential factor is same in both the cases. Given R=8.314 J K-1 mol-1]
MEDIUM
JEE Main
IMPORTANT
A flask is filled with equal moles of A and B. The half lives of A and B are 100 s and 50 s respectively and are independent of the initial concentration. The time required for the concentration of A to be four times that of B is____s.
(Given : ln2=0.693)