MEDIUM
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It is true that :  

(1) A zero order reaction is a single step reaction.  

(2) A second order reaction is always a multistep reaction.  

(3) A first order reaction is always a single step reaction.

(4) A zero order reaction is a multistep reaction.

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Important Questions on Chemical Kinetics

EASY
The units for the rate constant and the rate of reaction are same for a reaction. What will be the order of the reaction?
EASY
One gram of (A) decays by β-emission to 0.125 g in 200 years. The half-life period of the reaction is
EASY
A first order reaction takes 40 minutes for 30% completion. Calculate the half life of reaction.
HARD

What will be the order of the reaction for hydrolysis of methyl acetate with NaOH by using the data provided?

Time (min)                       0       5       10       15
Volume of acid (mL)   10.12    6.24    1.40   0.981

EASY
For the elementary reaction MN, the rate of disappearance of M increases by a factor of 8 upon doubling the concentration of M. The order of the reaction with respect to M is
EASY
Hydrolysis of ester is a first order reaction. For this reaction, the correct statement is
HARD
Gaseous cyclobutene isomerizes to butadiene in a first order process which has a 'K' value of 3.3×10-4 s-1 at 153°C. The time in minutes it takes for the isomerization to proceed 40% to completion at this temperature is_____. (Rounded off to the nearest integer)
MEDIUM
Half-life period for a first order reaction is 10 minutes. How much time is required to change the concentration of the reactants 0.08 M to 0.01 M?
EASY
The reaction 2NO g+O2 g2NO2 g is of the first-order. If the volume of the reaction vessel is reduced to 1/3, the rate of the reaction would be
MEDIUM

For the chemical reaction

2O33O2, the reaction proceeds as follows

O3O2+O (Fast)

O+O32O2, (Slow)

the rate law expression should be given as

MEDIUM
The rate of a reaction is found to depend upon two concentration variables. What should be the order of the reaction?
HARD
In the reaction,

P + Q R + S

the time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The concentration of Q varies with reaction time as shown in the figure.The overall order of the reaction is:

Question Image  
EASY
For a certain reaction between X and Y, the order with respect to X is 3 and that with respect to Y is 4. If the concentrations of both X and Y are tripled. the rate of reaction will increase by a factor of ________
EASY
It takes 1h for a first order reaction to go to 50% completion. The total time required for the same reaction to reach 87.5%  completion will be
MEDIUM
Graph plotted between log t1/2 versus log concentration a is a straight line. What conclusion can you draw from the graph?

Question Image

n= order of reaction

EASY

For a reaction 2H2O2

2H2O2Alkaline mediumI-2H2O+O2

The proposed mechanism is as given below:

1. H2O2+I-H2O+IO- (slow)

2. H2O2+IO-H2O+I-+O2 (fast)

 Write the overall order of a reaction.

HARD
For the following reaction 2X+YkP the rate of reaction is d[P]dt=k[X]. Two moles of X are mixed with one mole of Y to make 1.0 L of solution. At 50 s, 0.5 mole of Y is left in the reaction mixture. The correct statement(s) about the reaction is(are) (Use: ln 2=0.693)
MEDIUM
The time required for 60% completion of a first order reaction is 50 min. The time required for 93.6% completion of the same reaction will be
MEDIUM
Decomposition of H2O2 follows a first order reaction. In fifty minutes the concentration of H 2 O 2 decreases from 0.5 to 0.125 M in one such decomposition. When the concentration of H2O2 reaches 0.05 M , the rate of formation of O2 will be:
MEDIUM
What is the correct difference between first and second order reactions?