HARD
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Match the alkyl halide reacting with reagent given in Column I with their respective substituted product given in  Column II and choose the correct option from the codes given below: 

Column I

Column II
a KCN 1) RH
b AgCN 2) RCN
c KNO2 3)  RNC
d LiAlH4 4) R-O-N=O

 

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Important Questions on Haloalkanes and Haloarenes

MEDIUM

The major product of the following reaction is:

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EASY

The reagent required for the following two step transformation are

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EASY
The increasing order of the reactivity of the following halides for the SN1 reaction is

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MEDIUM

The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is:

(i) Question Image

(ii)  Question Image

(iii) Question Image

(iv) Question Image

MEDIUM
In SN2 reactions, the correct order of reactivity for the following compounds :
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is :
MEDIUM
Neopentyl bromide, undergoes dehydrohalogenation to give alkenes even though it has no βH . This is due to
MEDIUM
The major product obtained in the following reaction is,

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MEDIUM
The major product of the reaction between CH3CH2ONa and CH33CCl in ethanol is
MEDIUM
How do you distinguish chlorobenzene from benzyl chloride?
EASY
Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction?
MEDIUM

The major product of the following reaction is:
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MEDIUM
The major product of the following reaction is:

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EASY
Which of the following, upon treatment with tert-BuONa  followed by addition of bromine water, fails to decolourize the colour of bromine?
MEDIUM
The order of SN1 reactivity in aqueous acetic acid solution for the compounds
(1) H 3 C - C || O - C H 2 - C l

(2) H3C-CH2-CH2-Cl

(3) H3C3C-Cl

is
MEDIUM
In a nucleophilic substitution reaction :  R - Br + Cl - DMF R - Cl + Br - ,  which one of the following undergoes complete inversion of configuration ?
EASY
Consider the reaction
CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr
This reaction will be the fastest in
MEDIUM
Compound (A), C8H9Cl, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (A) gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).
EASY
For the following reactions:
a. CH3CH2CH2Br + KOH CH3CH=CH2+ KBr+ H2O 
b.
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c.
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Which of the following statements is correct?