MEDIUM
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Earn 100

Match the following
  Column-I Complex   Column-II
Structure / Geometry / Property
(A) NiCN42- (I) Tetrahedral / Paramagnetic
(B) NiCO4 (II) Tetrahedral / Diamagnetic
(C) NiCl42- (III) Square planar / Diamagnetic

The correct match is

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Important Questions on Coordination Compounds

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The magnetic moment of the high spin complex is 5.92 BM. What is the electronic configuration?
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IMPORTANT

The coordination complex CuH2O62+ has one unpaired electron, which of the following statements are true?

(i) The complex is octahedral.

(ii) The complex is an outer orbital complex.

(iii) The complex is diamagnetic.

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The reaction of aqueous NiH2062+ Is performed by the addition of a bidentate ligand ethane-1, 2, diamine (en)
Match the following
  NiH2O62+: en molar ratio   Colour of the product
A 1 : 1 I Pale blue
B 1 : 2 II Blue / Purple
C 1 : 3 III Violet
D   IV Green

The correct match is

HARD
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IMPORTANT

Which of the following molecules/ions can exhibit isomerism:

A) Tetrahedral  NiCl2Br22-
B) Square planar PtNH32Cl2
C) Octahedral    CoNH33Cl3
D)  Square planar  PdNH33Br+
E) Octahedral  Co(en)33+

Here, en=1, 2-di amino ethane.

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The oxidation number of central metal in PtNH32ClNO2 and CoCl2(en)2, respectively, are
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According to Valence Bond Theory, the number of unpaired electrons present in MnCl63-, Fe(CN)63- and CoC2O43-, respectively, are