MEDIUM
AS and A Level
IMPORTANT
Earn 100

Name the mechanism of the reaction tri-substituted halogenoarene produced if methylbenzene and bromine were boiled in the presence of UV light.

Important Questions on Benzene and its Compounds

MEDIUM
AS and A Level
IMPORTANT

Copy and complete the equation below, which can be used to show the nitration of methylbenzene:

C6H5CH3+NO2+_____+_____.

MEDIUM
AS and A Level
IMPORTANT

Copy and complete the equation below, which can be used to show the nitration of methylbenzene:

C6H5CH3+HNO3H2SO4_____+_____.

MEDIUM
AS and A Level
IMPORTANT

Copy and complete the two equations below, which can both be used to show the nitration of methylbenzene:

i. C6H5CH3+NO2+_____+_____.

ii. C6H5CH3+HNO3H2SO4_____+_____.

Name the possible mono-substituted products in parts i and ii.

EASY
AS and A Level
IMPORTANT
2,4-dinitromethylbenzene and 2,4,6-trinitromethylbenzene are formed on further nitration of methylbenzene. Draw the displayed formula of each compound.
EASY
AS and A Level
IMPORTANT
Benzene also undergoes electrophilic substitution when refluxed with fuming sulphuric acid for several hours. This is called sulphonation. The electrophile is the SO3 molecule and the product formed is benzenesulphonic acid, C6H5SO3H. Suggest which atom in the SO3 molecule accepts an electron pair in the mechanism of sulphonation.
EASY
AS and A Level
IMPORTANT
Benzene also undergoes electrophilic substitution when refluxed with fuming sulphuric acid for several hours. This is called sulphonation. The electrophile is the SO3 molecule and the product formed is benzenesulphonic acid, C6H5SO3H. Write an equation in the style of SO3 molecule accepts an electron pair in the mechanism of sulphonation of benzene to form benzenesulphonic acid.
EASY
AS and A Level
IMPORTANT

Copy and complete the equation, which can be used to show the alkylation of benzene to produce the mono-substituted products.

C6H6+CH3CH2CH2Cl_____+_____.

EASY
AS and A Level
IMPORTANT

Copy and complete the equation, which can be used to show the acylation of benzene to produce the mono-substituted products.

C6H6+CH3CH2CH2CH2COCl_____+_____.