MEDIUM
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Phenol on treatment with CO2 in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with CH3CO2O in the presence of catalytic amount of H2SO4 produces

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Important Questions on Aldehydes, Ketones and Carboxylic Acids

MEDIUM
Acetic anhydride reacts with diethyl ether in the presence of anhydrous AlCl3 to give
EASY

Acid strength given below the correct decreasing order will be :

MEDIUM
An organic compound A upon reacting with NH3 gives B. On heating, B gives C. C in presence of KOH reacts with Br2 to give CH3CH2NH2. A is :
MEDIUM
α- chlorosodium acetate on boiling with aqueous sodium nitrite gives
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Which of the following acid will form an (a) Anhydride on heating and (b) Acid imide on strong heating with ammonia?
EASY
In the presence of a small amount of phosphorous, aliphatic carboxylic acid reacts with chlorine or bromine to yield a reaction in which, α-hydrogen is been replaced by halogen. This reaction is known as
EASY

Give the chemical equation for the reaction of CH3COOH with following:

LiAlH4

HARD
List-I includes starting materials and reagents of selected chemical reactions. List-II gives structures of compounds that may be formed as intermediate products and/or final products from the reactions of List-I.
List-I List-II

(I)
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P
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(II)
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Q
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(III)
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R
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(IV)
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S
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T
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U
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Which of the following options has the correct combination considering List-I and List-II?
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The decreasing order of ease of alkaline hydrolysis for the following esters is
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MEDIUM
Propanoic acid undergoes HVZ reaction to give chloropropanoic acid. The product obtained is
MEDIUM
The total number of isomeric linear dipeptides which can be synthesised from racemic alanine is
EASY
Which of the following acids, does NOT undergo Hell-Volhard-Zelinsky reaction?
HARD
In the reaction,

CH 3 COOH LiAlH 4 A PCl 5 B Alc. KOH C ,

the product C is :
MEDIUM
Which one of the following esters gets hydrolyzed most easily under alkaline conditions?
MEDIUM
In the following reaction sequence, the correct structures of E, F and G are

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[*implies13C labelled carbon]