HARD
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Separation of a mixture of o -nitrophenol and p -nitrophenol can be effected by steam distillation. This is based on the fact(s) that

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Important Questions on Chemical Bonding and Molecular Structure

MEDIUM

Consider the following molecules and statements related to them:

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(a) (B) is more likely to be crystaline than (A)

(b) (B) has higher boiling point than (A)

(c) (B) dissolves more readily than (A) in water

Identify the correct option from below:

EASY
Which one of the following compounds shows the presence of intramolecular hydrogen bond?
MEDIUM
If the boiling point of H2O is 373 K, and  the boiling point of H2S will be :
EASY
Among the compounds I - IV, the compound having the lowest boiling point is:

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MEDIUM
Which of the following has the strongest H-bond ?
MEDIUM
Among the compounds A and B with molecular formula C9H18O3, A is having higher boiling point than B. The possible structures of A and B are:
MEDIUM
The increasing order of the boiling points for the following compounds is:

IC2H5OH      IIC2H5Cl    IIIC2H5CH3   IV C2H5OCH3
HARD
Hydrogen bonding plays a central role in the following phenomena:
EASY

Given below are two statements:

Statement I : o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.

Statement II : o-Nitrophenol has high melting due to hydrogen bonding.

In the light of the above statements, choose the most appropriate answer from the options given below:

EASY
Among the following four aromatic compounds, which one will have the lowest melting point?
EASY

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Dipole-dipole interactions are the only non-covalent interactions, resulting in hydrogen bond formation.

Reason R : Fluorine is the most electronegative element and hydrogen bonds in HF are symmetrical.

In the light of the above statements, choose the most appropriate answer from the options given below:

MEDIUM
Which of the following does not form intra-molecular hydrogen bonding?
EASY
Of the following, which species is primarily obtained in a solution containing KHF2 ?
MEDIUM
The boiling point of hydrogen halides varies in the order
EASY
In which of the following substances will hydrogen bond be strongest?
MEDIUM
HF has highest boiling point among hydrogen halides, because it has:
EASY
What is the actual volume occupied by water molecules present in 20 cm3 of water?
MEDIUM
The variation of the boiling points of the hydrogen halides is in the order HF>HI>HBr>HCl . Which of the following option explains the higher boiling point of hydrogen fluoride?