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The chemical formula of benzenediazonium chloride is 

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Important Questions on Amines

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Explain the following :

Diazonium salts of aromatic amines are more stable than those of aliphatic amines.

EASY
Which of the following will be most stable diazonium salt RN2+X- ?
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Give the structures of A and B in the following sequence of reactions:

C6H5N2+Cl- CuCN A H2O/H+ B

HARD

 Three isomers A, B and C (mol. formula C8H11N  ) give the following results:

A and CDianotizationP+Q(ii) acidationKMnO4+H+(i) HydrolydsR product of A+S product of C

R has lower boiling point than S

BC6H5SO2Cl alkali-insoluble product

A, B and C, respectively are:

EASY
When aniline is treated with sodium nitrite and hydrochloric acid at 0°C, it gives
HARD
The major product of the reaction is


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HARD
An organic compound 'A' contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound 'A' with standard base indicates that the molecular weight of 'A' is 131±2. When a sample of 'A' is treated with aq. NaOH, a liquid separates which contains N but not Cl. Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound 'A' is
MEDIUM

The correct sequence of correct reagents for the following transformation is :-

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The correct stability order of the following diazonium salt is

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HARD

In the following reaction sequence, [C] is :

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MEDIUM
What is the correct sequence of reagents used for converting nitrobenzene into m-dibromobenzene?

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EASY
Which of the following will be the most stable diazonium salt RN2+X-?
EASY

A and B in the following reactions are:

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In the above chemical reaction, intermediate "X" and reagent/condition "A" are :

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What is the major product "P" of the following reaction ?

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Consider the above reaction, the Product "P" is :

MEDIUM
Given below are two statements:
Statement I:
Primary aliphatic amines react with HNO2 to give unstable diazonium salts.
Statement II :
Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K. In the light of the above statements, choose the most appropriate answer from the options given below 
EASY

In the chemical reactions,

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The compounds A and B, respectively, are

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An organic compound C3H9N A when treated with nitrous acid gave an alcohol and N2 gas was evolved. A on warming with CHCl3 and caustic potash gave C, which on reduction gave isopropylmethylamine. Predict the structure of A.