EASY
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The conductivity of strong electrolyte

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Important Questions on Electrochemistry

MEDIUM
Which of the following electrolytic solution has the least specific conductance
HARD
The equivalent conductance of NaCl at concentration C and at infinite dilution are λ C and λ , respectively. The correct relationship between λ C and λ is given as :
(where the constant B is positive)
EASY
Consider the statements S1 and S2 :
S1 : Conductivity always increases with decreases in the concentration of electrolyte.
S2 : Molar conductivity always increases with decreases in the concentration of electrolyte.
The correct option among the following
MEDIUM
What is the molar conductivity of 0·1 M NaCl if its conductivity is 1.06×10-2Ω-1 cm-1?
HARD
Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.
EASY
The pair of electrolytes that possess same value for the constant (A) in the Debye - Huckel - Onsagar equation, λm=λm°-AC is
HARD
Which one of the following graphs between molar conductivity Λm versus C is correct?
EASY
The molar conductivities of NaOH,NaCl and BaCl2, at infinite dilution are 2.481×10-2 Sm2 mol-11.265×10-2 Sm2 mol-1 and 2.800×10-2 Sm2 mol-1 respectively. The molar conductivity of BaOH2. at infinite dilution will be
EASY

Following figure shows dependence of molar conductance of two electrolytes on concentration. Λm0 is the limiting molar conductivity.

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The number of Incorrect statement(s) from the following is _____

(A) Λm0 for electrolyte A is obtained by extrapolation
(B) For electrolyte B,   Λm Vs c  graph is a straight line with intercept equal to Λm0
(C) At infinite dilution, the value of degree of dissociation approach zero for electrolyte B.
(D) Λm for any electrolyte A or B can be calculated using λ° for individual ions.

HARD
Resistance of 0.2 M solution of an electrolyte is 5 0  Ω . The specific conductance of the solution is 1.4 S m -1 . The resistance of 0.5 M solution of the same electrolyte is 28 0  Ω . The molar conductivity of 0.5 M solution of the electrolyte in S m 2 mol -1 is :
HARD
Among the following, the plot that correctly represents the conductometric titration of 0.05 M H2SO4 with 0.1 M NH4OH is
MEDIUM

Calculate the degree of dissociation () of acetic acid, if its molar conductivity (Ʌm) is 39.05 S cm2 mol-1

Given: λ°(H+)=349.6 S cm2 mol-1 and λ°(CH3COO-)=40.9 S cm2 mol-1.

MEDIUM
At a particular temperature, the ratio of molar conductance to specific conductance of 0.01 M NaCl solution is
EASY

The variation of molar conductively with concentration of an electrolyte (X) in aqueous solution is shown in the given figure.

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The electrolyte X is :

EASY
What are the units of equivalent conductivity of a solution?
EASY
The resistance of 0.01M KCl solution at 298 K is 1500 Ω. If the conductivity of 0.01M KCl solution at 298 K is 0.1466×10-3 S cm-1. The cell constant of the conductivity cell in cm-1 is
EASY
If the resistivity of 0.1 M KCl solution is 50 Ω cm. What is its molar conductivity?
MEDIUM
The molar conductivity of a 0.5 mol dm-3 solution of AgNO3 with electrolytic conductivity of 5.76×10-3 S cm-1 at 298 K
EASY

The electronic conductivity does not depend on

EASY
Aqueous solution of which of the following compounds is the best conductor of electric current?