The correct order of Sulphur oxygen bond order in ${\mathrm{SO}}_3,{ \mathrm{S}}_2{\mathrm{O}}_3^{2-}$ and ${\mathrm{SO}}_4^{2-}$ are

Increasing order of boiling points in the following compounds is:

$\underset{\left(\mathrm{i}\right)}{{\mathrm{CH}}_3\mathrm{COOH}} \underset{\left(\mathrm{ii}\right)}{ {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CHO}} \underset{\left(\mathrm{iii}\right)}{{\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2\mathrm{OH}} \underset{\left(\mathrm{iv}\right)}{{\mathrm{CH}}_3{\mathrm{COCH}}_3}$