HARD
JEE Advanced
IMPORTANT
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The plot given below shows P-T curves (where, P is the pressure and T is the temperature) for two solvents X and Y and isomolal solutions of NaCl in these solvents. NaCl completely dissociates in both the solvents.

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On the addition of equal number of moles of a non-volatile solute S in equal amount (in kg) of these solvents, the elevation of boiling point of solvent X is three times that of solvent Y. The solute S is known to undergo dimerization in these solvents. If the degree of dimerization is 0.7 in the solvent Y, the degree of dimerization in the solvent X is _______.

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Important Questions on Solutions

HARD
JEE Advanced
IMPORTANT
Benzene and naphthalene form an ideal solution at room temperature. For this process, the true statement(s) is (are)
MEDIUM
JEE Advanced
IMPORTANT
The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05 . If the density of the solution is 1.2 g cm-3 , the molarity of urea solution is _______
(Given data: Molar masses of urea and water are 60 g mol-1 and 18 g mol-1 , respectively)
MEDIUM
JEE Advanced
IMPORTANT
Pure water freezes at 273 K and 1 bar pressure. The addition of 34.5 g of ethanol to 500 g of water changes the freezing point of the solution. Use the freezing point depression constant of water as 2 K kg mol-1. The figures shown below represent the plots of vapour pressure (V.P.) versus temperature (T). [Molecular weight of ethanol is 46 g 46 g mol-1]

Among the following, the option representing a change in the freezing point is
HARD
JEE Advanced
IMPORTANT
Mixture(s) showing positive deviation from Raoult's law at 35oC is (are)
HARD
JEE Advanced
IMPORTANT

On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapor pressure decreases from 650 mm Hg to 640 mm Hg. The depression of freezing point of benzene (in K ) upon addition of the solute is _______

(Given data: Molar mass and the molal freezing point depression constant of benzene are 78 g mol-1 and 5.12 K kg mol-1, respectively)

Give your answer up to three significant figures.

HARD
JEE Advanced
IMPORTANT
Liquids A and B form ideal solution over the entire range of composition. At temperature T, equimolar binary solution of liquids A and B has vapour pressure 45 Torr . At the same temperature, a new solution of A and B having mole fractions xA and xB, respectively, has vapour pressure of 22.5 Torr. The value of xAxB, in the new solution is ____.

(Given that the vapour pressure of pure liquid A is 20 Torr at temperature T)
MEDIUM
JEE Advanced
IMPORTANT
For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole fraction of M in solution is shown in the following figure, Here, XL and XM represent mole fractions of L and M, respectively, in the solution. The correct statement(s) applicable to this system is(are) -

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