MY and N Y 3 , two nearly insoluble salts, have the same K s p values of 6.2 × 10 - 13 at room temperature. Which statement would be true in regard to MY and N Y 3 ?

The molar solubility of MY in water is less than that of N Y 3 .

The molar solubilities of MY and N Y 3 in water are identical.

The salts MY and N Y 3 are more soluble in 0.5 M KY than in pure water.

The addition of the salt of KY to solution of MY and N Y 3 will have no effect on their solubilities.

MEDIUM

Earn 100

The presence of $N H_{4} C l$ in the test solution while precipitating group III-A hydroxides (in qualitative inorganic analysis) helps in

50% studentsanswered this correctly

Important Questions on Equilibrium

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

What is the molar solubility of

A I {(O H)}_{3}

0.2

M N a O H

solution? Given that, solubility product of

Al {(O H)}_{3} = 2.4 \times 10^{- 24}

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

Zirconium phosphate

[{Zr}_{3} {({PO}_{4})}_{4}]

dissociates into three zirconium cations of charge

+ 4

and four phosphate anions of charge

- 3

. If molar solubility of zirconium phosphate is denoted by

s

and its solubility product by

K_{sp}

then which of the following relationship between

s

and

K_{sp}

is correct ?

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

If solubility product of

Z r_{3} {(P O_{4})}_{4}

is denoted by

K_{s p}

and its molar solubility is denoted by

S

, then which of the following relation between

S

and

K_{s p}

is correct?

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The

K_{s p}

for the following dissociation is

1.6 \times 10^{- 5}

{P b C l}_{2 (s)} ⇌ P b_{(a q)}^{2 +} + 2 C l_{(a q)}^{-}

Which of the following choices is correct for a mixture of

300 mL, 0 .134 M Pb {({NO}_{3})}_{2}

and

100 m L,

0.4 M N a C l ?

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The

K_{sp}

{Ag}_{2} {CrO}_{4}, AgCl, AgBr

and

A g I

are respectively,

1.1 \times 10^{- 12}, 1.8 \times 10^{- 10}, 5.0 \times 10^{- 13}, 8.3 \times 10^{- 17}

. Which one of the following salts will precipitate last if

A g N O_{3}

solution is added to the solution containing equal moles of NaCl, NaI, NaBr and

N a_{2} C r O_{4}

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The molar solubility of

C d {(O H)}_{2}

1.84 \times 10^{- 5} M

in water. The expected solubility of

C d {(O H)}_{2}

in a buffer solution of

p H = 12

is:

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

An aqueous solution contains an unknown concentration of

{Ba}^{2 +}

. When

50 mL of a 1 M

solution of

{Na}_{2} {SO}_{4}

is added,

{BaSO}_{4}

just begins to precipitate. The final volume is

500 mL

. The solubility product of

{BaSO}_{4}

1 \times 10^{- 10}

. What is the original concentration of

{Ba}^{2 +}

EASY

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

HCl

was passed through a solution of

{CaCl}_{2}

{MgCl}_{2}

and

NaCl

. Which of the following compound(s) crystallise(s)?

EASY

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The solubility of

A g C l (s)

with solubility product

1.6 \times 10^{- 10}

0.1 M N a C l

solution would be

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The

K_{sp}

{Ag}_{2} {CrO}_{4}

1.1 \times 1 0^{- 12}

298 K

. The solubility (in

mol L^{- 1}

) of

{Ag}_{2} CrO_{4}

in a

0.1 M {AgNO}_{3}

solution is

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The stoichiometry and solubility product of a salt with the solubility curve given below is, respectively:

Question Image

EASY

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

K_{sp}

{Ag}_{2} {CO}_{3}

8 \times 10^{- 12}

, the molar solubility of

{Ag}_{2} {CO}_{3}

0 .1 M {AgNO}_{3}

is:

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The solubility product of

C r {(O H)}_{3}

298 K

6.0 \times 10^{- 31} .

The concentration of hydroxide ions in a saturated solution of

C r {(O H)}_{3}

will be

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

pH of a saturated solution of

C a {(O H)}_{2}

9

. The solubility product

(K_{s p})

C a {(O H)}_{2}

is:

EASY

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

Solubility of

AgCl

is least in

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

An acidified solution of

0.05 M {Zn}^{2 +}

is saturated with

0.1 M H_{2} S

. What is the minimum molar concentration

(M)

H^{+}

required to prevent the precipitation of

ZnS

? Use

K_{sp} (ZnS) = 1.25 \times 10^{- 22}

and overall dissociation constant of

H_{2} S, K_{NET} = K_{1} K_{2} = 1 \times 10^{- 21}

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

Find out the solubility of

Ni {(OH)}_{2}

0.1 M NaOH

. Given that the ionic product of

Ni {(OH)}_{2}

2 \times 10^{- 15}

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

Concentration of the

{Ag}^{+}

ions in a saturated solution of

{Ag}_{2} C_{2} O_{4}

2.2 \times 10^{- 4} mol L^{- 1}

. Solubility product of

{Ag}_{2} C_{2} O_{4}

is:

HARD

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

The solubility of a salt of weak acid

(AB) at pH = 3 is Y \times 10^{- 3} mol L^{- 1}

. The value of

Y

is ____(Nearest integer). (Given that the value of solubility product of

AB (K_{sp}) = 2 \times 10^{- 10}

, and the value of ionisation constant of

HB (Ka) = 1 \times 10^{- 8}

)

MEDIUM

Chemistry>Physical Chemistry>Equilibrium>Applications of Solubility Product and Common Ion Effect

MY and

N Y_{3}

, two nearly insoluble salts, have the same

K_{s p}

values of

6.2 \times 10^{- 13}

at room temperature. Which statement would be true in regard to MY and

N Y_{3}

The presence of NH4Cl in the test solution while precipitating group III-A hydroxides (in qualitative inorganic analysis) helps in

Important Questions on Equilibrium

Learn and Prepare for any exam you want !

The presence of $N H_{4} C l$ in the test solution while precipitating group III-A hydroxides (in qualitative inorganic analysis) helps in