How are XeF 2 and XeF 4 prepared? Give their structures.

Xenon difluoride is prepared by the combination of xenon and excess of fluorine at 673 K and 1 bar pressure. Xe + F 2 → 1 bar 673 K XeF 2 s Xenon tetrafluoride is prepared by the combination of xenon and excess of fluorine in the ratio of 1 : 5 at 873 K and 7 bar pressure as given below: Xe + 2 F 2 → 7 bar 873 K XeF 4 s XeF 2 has a linear structure with bond angle of 180 ° . Xenon atom has two bond pairs and three lone pairs of electrons. XeF 4 has square planar structure with bond angle of 90 ° . Xenon atom has four bond pairs and two lone pairs of electrons. The structures are as given below:

Why are halogens coloured.

Most of the halogens are coloured because they absorb radiations which are in the visible region which in turn excite the valence electrons to higher energy levels. As the amount of energy which is required to excite the electrons to a higher level is different for different halogens, each halogen has a different colour.

Why does nitrogen show catenation properties less than phosphorus?

Catenation is the property of bonding of atoms of the same element into a series to form a chain. Catenation is shown by phosphorous more than nitrogen. This is due to the reason that the N - N single bond is relatively weaker as compared to the P - P single bond. The nitrogen atom is small. So, there is greater repulsion of electron density of two nitrogen atoms, thereby weakening the N - N single bond. Phosphorous has a larger atomic size, so it has less repulsion of electron density of two phosphorous atoms. Therefore, the P - P single bond is stronger.

E M B I B E

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 12

EASY

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IMPORTANT

Earn 100

What do you understand by the term inert pair effect?

Important Questions on p-Block Elements

MEDIUM

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 13

Explain why

{NH}_{3}

is basic while

{BiH}_{3}

is only feebly basic.

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 14

Arrange the hydrides of group- $15$ in the increasing order of basic strength and decreasing order of reducing character.

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 15

${PH}_{3}$ is a weaker base than ${NH}_{3}$ . Explain.

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 16

A hydride of group- $15$ elements dissolves in water to form a basic solution. This solution dissolves the $AgCl$ precipitate. Name the hydride. Write the chemical equations involved.

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 17

What happens when white phosphorus is heated with conc $NaOH$ in an inert atmosphere of ${CO}_{2}$ ?

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IMPORTANT

Intermediate Second Year Chemistry>Chapter 6 - p-Block Elements>Questions>Q 18

Why does