HARD
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When 10 ml mixture of N2, CO2 and CO with mole %, 30 %, 40 % and 30 % respectively is combusted in Eudiometer tube and when resulting mixture is pass through Turpentine oil, contraction of 30 ml is observed and when remaining mixture is pass through KOH solution then contraction of x ml is observed, what is the value of x ?

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Important Questions on States of Matter : Gases and Liquids

HARD
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume, for complete combustion. After combustion, the gases occupy 345 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:
(Assume complete combustion of reactant)
HARD
16 mL of a gaseous aliphatic compound CnH3nOm was mixed with 60 mLO2 and sparked. The gas mixture on cooling occupied 44 mL. After treatment with KOH solution the volume of gas remaining was 12 mL. Deduce the formula of compound
MEDIUM
A 40 ml of a mixture of H2 and O2 at 18 °C and 1 atm pressure was sparked so that the formation of water was complete. The remaining pure gas had a volume of 10 ml at 18 °C and 1 atm pressure. If the remaining gas was H2, the mole fraction of H2 in the 40 ml mixture is:
HARD
280 mL of sulphur vapour at normal temperature and pressure weighs 3.2 g. Determine the molecular formula of the sulphur vapour.
HARD
A mixture of methane, propane and carbon monoxide contains 36.5 % propane by volume. If its 200 ml are burnt in excess of O2, the volume of CO2 formed is :
HARD
On passing 25 mL of a gaseous mixture of N2 and NO over heated copper, 20 mL of the gas remained. Calculate the percentage of each gases in the mixture.
HARD
What do you mean by eudiometry? How will you measure CO2 gas by absorption of CO2 gas by alkaline KOH solution in eudiometry?
MEDIUM

Represent the union of two sets by Venn diagram for each of the following.

X={x | x is a prime number between 80 and 100}

Y={y | y is an odd number between 90 and 100}

MEDIUM
0.2 mol sample of hydrocarbon CXHY yields, after complete combustion, with excess O2 gas, 0.8 mol CO2  and 0.1 mol H2O. Hence, hydrocarbon is:
EASY

When 100 mL of an O2-O3 mixture was passed through turpentine, there was a reduction in volume by 20 mL. If 100 mL of such a mixture is heated, what will be the increase in volume (in ml) ?

[Hint: O3 is absorbed by turpentine]

HARD

5.22×10-4 mol of a gas containing H2, O2 and N2 exerted a pressure of 67.4 mm in a certain standard volume. The gas was passed over a hot platinum filament which combined H2 and O2 into H2O which was frozen out. When the gas was returned to the same volume, the pressure was 14.3 mm. Extra oxygen was added to increase the pressure to 44.3 mm. The combustion was repeated, after which the pressure read 32.9 mm. What was the mole fraction of H2, O2 and N2 in the gas sample?

[Hint: 2 volumes of H2 combine with 1 volume of O2. In the first combustion, H2 is in excess, while in the second one, O2 is in excess]

HARD
10 ml of gaseous hydrocarbon is exploded with 100 ml O2. The residual gas on cooling is found to measure 95 ml of which 20 ml is abosorbed by KOH and the reminder by alkaline pyrogallol. The formula of the hydrocarbon is:
HARD
The explosion of a mixture containing one volume of a gas being studied and 1 volume of H2 yielded 1 volume of water vapor and 1 volume of N2, with the volumes measured under identical conditions. Find the formula of the gas under study.
HARD
10 ml of a gaseous hydrocarbon was exploded with excess of O2. On cooling, the reaction mixture volume was reduced by 10 ml, while on adding KOH, the volume was reduced by 20 ml. Molecular formula of hydrocarbon is:
HARD

Ten millilitres of a gaseous hydrocarbon was burnt completely in 80 mL of O2 at STP. The volume of the remaining gas is 70 mL. The volume became 50 mL on treatment with NaOH. The formula of the hydrocarbon is:

HARD
One volume of a compound of carbon, hydrogen and oxygen was exploded with 2.5 volumes of oxygen. The resultant mixture contained 2 volumes of water vapour and 2 volumes of carbon dioxide. All the volumes were measured in identical conditions. Determine the formula of the compound.
HARD
20 mL of a mixture containing C2H2 and CO was exploded along with 30 mL of oxygen. The gases after the reaction had a volume of 34 mL. On treatment with KOH, 8 mL of oxygen remained. Calculate the composition of the mixture.
MEDIUM
25 ml of O2 contracts to 20 ml when subjected to silent electric discharge in an ozoniser. What further contraction would be observed if the partially ozonised oxygen is treated with oil of cinnamon (which absorbs ozone)? All volumes are reported at the same temperature and pressure.
MEDIUM
For complete combustion of 5 L of an alkane, 25 L of oxygen is required. Which of the following is this alkane, if all volumes are measured at constant temperature and pressure?