MEDIUM
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When phenol is heated with phthalic anhydride in presence of conc. H2SO4, an important acid-base indicator is formed. Identify its structure.

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Important Questions on Hydroxy Compounds and Ethers

MEDIUM
A compound that undergoes bromination easily is:
HARD

What is Z in the following sequence of reactions?
PhenolZn dustXCH3Cl/Anhydrous AlCl3YAlkaline KMnO4Z

MEDIUM

Assertion(A):-OH group of phenol is ortho, para directing in electrophilic substitutions

Reason (R):-OH group stabilises the arenium ion formed by the ortho, para attack of the electrophile

The correct answer is

HARD
An organic compound A of molecular formula C6H6O gives violet colour with neutral ferric chloride solution. Compound A when heated with zinc dust gives a hydrocarbon B.  Also compound A reacts with phthalic anhydride and concentrated sulphuric acid to give compound C of molecular formula C20H14O4. Identify A, B and C. Explain the reactions.
EASY

The major product P formed in the following reaction is

HARD
Phenol                     Zn                    distillation A                    conc. HNO3                   conc. H2SO4 at 60°C B              Zn             NaOH C

In the above reaction, compounds
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What is the reactant [X] which produces cyclohexanone and formaldehyde on reaction with HIO4 ?
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The conversion of phenol into salicylic acid is done via_____reaction.

HARD
Which of the following statements is/are correct ?
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Which one of the following compounds would undergo nitration with the greatest ease?
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Phenol can be distinguished from ethanol by the reactions with _____.
EASY
The catalytic hydrogenation of phenol gives _____.
HARD

Ortho-salicylic acid is frequently used as a precursor for the preparation of aspirin. Which of the following reactions can be used to prepare ortho-salicyclic acid from phenol?

HARD
When o-or p-phenol sulphonic acid is treated with bromine water, the product formed is
MEDIUM
Benzoylation of phenol in alkaline medium is known as
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Assertion: Phenol is more reactive than benzene towards electrophilic reactions.

Reason: The + R effect of OH group increases the electron density on benzene nucleus.