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Which is the correct basic strength order of the following compounds?

i)

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ii)

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iii)

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iv)

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Important Questions on Organic Compounds Containing Nitrogen

HARD
The product(s) of the following reaction sequence is(are)

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EASY
Which of the following compounds will form significant amount of meta product during mono-nitration reaction?
EASY
The nitrosation of N,N-dimethylaniline takes place through the attack of electrophile:
EASY
Describe a method for the identification of primary, secondary and tertiary amines. Also, write chemical equations of the reactions involved.
MEDIUM
Among the following compounds, the increasing order of their basic strength is:

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MEDIUM
The amine which reacts with p-toluene sulphonyl chloride to give a clear solution which on acidification gives insoluble compound is
HARD

Aniline reacts with mixed acid (conc. HNO3 and conc. H2SO4 ) at 288 K to give P (51 %), Q (47%) and R (2%) . The major product(s) of the following reaction sequence is (are)

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MEDIUM
Aniline reacts with excess Br2/H2O to give the major product
MEDIUM

What will be the major product in the following mononitration reaction?

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HARD
The compound  X C7H9N reacts with benzenesulfonyl chloride to give  Y C13H13NO2S which is insoluble in alkali. The compound X is
EASY
A mixture containing the following four compounds is extracted with 1 M HCl. The compound that goes to aqueous layer is:
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EASY

In the reaction sequence
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X and Y are, respectively,

MEDIUM
The test to distinguish primary, secondary and tertiary amines is:
HARD
The final product formed when methylamine is treated with NaNO 2 and HCl followed by hydrolysis is:
MEDIUM
A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass 390. The number of amino groups presents per molecule of the former compound is
HARD

The major product obtained in the following reaction is:
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MEDIUM

The major product formed in the reaction given below will be :

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