MEDIUM
JEE Main
IMPORTANT
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Which one of the following given graphs represents the variation of rate constant (k) with temperature (T) for an endothermic reaction?

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Important Questions on Chemical Kinetics

MEDIUM
JEE Main
IMPORTANT

The rate constants for decomposition of acetaldehyde have been measured over the temperature range 700-1000 K. The data has been analysed by plotting lnk vs 103 T graph. The value of activation energy for the reaction is kJmol-1. (Nearest integer) (Given : R=8.31 JK-1 mol-1)

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MEDIUM
JEE Main
IMPORTANT

For a first order reaction, the time required for completion of 90% reaction is 'x' times the half life of the reaction. The value of 'x' is

(Given: ln10=2.303 and log2=0.3010)

HARD
JEE Main
IMPORTANT
For a given chemical reaction γ1A+γ2Bγ3C+γ4D. Concentration of C changes from 10 mmol dm-3 to 20 mmol dm-3 in 10 s. Rate of appearance of D is 1.5 times the rate of disappearance of B which is twice the rate of disappearance A. The rate of appearance of D has been experimentally determined to be 9 mmol dm-3s-1. Therefore the rate of reaction is____mmol dm-3s-1. (Nearest Integer)
HARD
JEE Main
IMPORTANT
At 345 K, the half life for the decomposition of a sample of a gaseous compound initially at 55.5 kPa was 340 s. When the pressure was 27.8 kPa, the half life was found to be 170 s. The order of the reaction is - [integer answer]
MEDIUM
JEE Main
IMPORTANT
Catalyst A reduces the activation energy for a reaction by 10 kJ mol-1 at 300 K. The ratio of rate constants, kCatalysedk Uncatalysed is ex. The value of x is____[nearest integer] [Assume that the pre-exponential factor is same in both the cases. Given R=8.314 J K-1 mol-1]
MEDIUM
JEE Main
IMPORTANT
A flask is filled with equal moles of A and B. The half lives of A and B are 100 s and 50 s respectively and are independent of the initial concentration. The time required for the concentration of A to be four times that of B is____s.
(Given : ln2=0.693)
MEDIUM
JEE Main
IMPORTANT

The rate constant for a first order reaction is given by the following equation :

lnk=33.24-2.0×104 K T

The Activation energy for the reaction is given by kJmol-1. (In Nearest integer) (Given : R=8.3 J K-1 mol-1)

MEDIUM
JEE Main
IMPORTANT
It has been found that for a chemical reaction with rise in temperature by 9 K the rate constant gets doubled. Assuming a reaction to be occurring at 300 K, the value of activation energy is found to be kJmol-1. [nearest integer] (Given ln10=2.3,R=8.3 J K-1 mol-1,log2=0.30)