HARD
Earn 100

Which would undergo SN2 reaction faster in the following pair and why?

Ethyl bromide and tertiary butyl bromide

Important Questions on Halogen Derivatives

MEDIUM

The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is:

(i) Question Image

(ii)  Question Image

(iii) Question Image

(iv) Question Image

EASY
Which of the following, upon treatment with tert-BuONa  followed by addition of bromine water, fails to decolourize the colour of bromine?
MEDIUM
In a nucleophilic substitution reaction :  R - Br + Cl - DMF R - Cl + Br - ,  which one of the following undergoes complete inversion of configuration ?
MEDIUM
Increasing rate of SN1 reaction in the following compounds is:
(I)Question Image
(II) Question Image
(III)Question Image
(IV) Question Image
MEDIUM
How do you distinguish chlorobenzene from benzyl chloride?
MEDIUM
Increasing order of reactivity of the following compounds for SN1 substitution is:
Question Image
MEDIUM
The order of SN1 reactivity in aqueous acetic acid solution for the compounds
(1) H 3 C - C || O - C H 2 - C l

(2) H3C-CH2-CH2-Cl

(3) H3C3C-Cl

is
MEDIUM
Which one of the following is likely to give a precipitate with AgNO3 solution?
EASY
Consider the reaction
CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr
This reaction will be the fastest in
EASY

The reagent required for the following two step transformation are

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MEDIUM
The major product of the following reaction is:
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MEDIUM
Compound (A), C8H9Cl, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (A) gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).
MEDIUM
Which of the following potential energy (P.E.) diagrams represents the SN1 reaction?
HARD

The major product of the following reaction is:

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MEDIUM
An ‘Assertion’ and a ‘Reason’ is given below. Choose the correct answer from the following options:
Assertion A: Vinyl halides do not undergo nucleophilic substitution easily.
Reason R: Even though the intermediate carbocation is stabilized by loosely held π- electrons, the cleavage is difficult because of the strong bonding.
MEDIUM

The mechanism of Sn1 reaction is given as:

R-XRXR  XYR-Y+X              lon pair      Solvent                             Speparated ion                                      pair

A student writes general characteristics based on the given mechanism as :
(a) The reaction is favoured by weak nucleophiles.
(b) R would be easily formed if the substituents are bulky y
(c) The reaction is accompanied by recemization
(d) The reaction is favoured by non-polar solvents.

Which observations are correct?

HARD
The decreasing order of reactivity towards dehydrohalogenation E1 reaction of the following compounds is:
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EASY
The increasing order of the reactivity of the following halides for the SN1 reaction is

Question Image
MEDIUM
In SN2 reactions, the correct order of reactivity for the following compounds :
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is :