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Why allylic and benzylic carbocation are more stable than tertiary carbocation?

Important Questions on Organic Chemistry- Some Basic Principles and Techniques

HARD

Increasing order of stability of the resonance structure is:

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MEDIUM
Which one among the following resonating structures is not correct?
MEDIUM
Arrange the following compounds in order of decreasing acidity :
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EASY

The most acidic proton and the strongest nucleophilic nitrogen in the following compound

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respectively, are

EASY

The chlorine atom of the following compound

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that reacts most readily with AgNO3 to give a precipitate is

HARD
A solution of (-)1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of :
MEDIUM
Which of the following molecules is least resonance stabilized?
EASY
Consider the following compounds

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Hyperconjugation occurs in:
EASY

Which of the following statements is not correct for a nucleophile?

MEDIUM
In which of the following compounds, the C-Cl bond ionization shall give most stable carbonium ion?
MEDIUM
The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, due to 
MEDIUM
The correct sequence of reagents for the following conversion will be

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MEDIUM

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Among the given species the Resonance stabilised carbocations are:

EASY
The correct order of stability for the following alkoxides is:

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MEDIUM
In which of the following molecules, all atoms are coplanar?