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Write a short note on Finkelstein reaction.

Important Questions on Haloalkanes and Haloarenes

EASY

The following reaction,

R-X+NaIR-I+NaX  where, X=Cl,Br is known as

MEDIUM

The major product of the following reaction is:

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EASY
Identify the halogen exchange reaction from the following.
EASY
Which of the following compound gives only one monochloro product on its chlorination in presence of sunlight?
HARD
Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.
 
Column 1 Column 2 Column 3
(I) Toulene (i) NaOH/Br2 (P) Condensation
(II) Acetophenone (ii) Br2/hv (Q) Carboxylation
(III) Benzaldehyde (iii) CH3CO2O/CH3COOK (R) Substitution
(IV) Phenol (iv) NaOH/CO2 (S) Haloform
The only CORRECT combination in which the reaction proceeds through radical mechanism is
MEDIUM

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Identify the reagent(s) 'A' and condition(s) for the reaction :

MEDIUM
When benzyl alcohol is reacted with concentrated HBr, produces the product  P . The product  P on reaction with KCN, gives Q  The product Q on heating with H3O+ generates R. The molecular formula of R is:
EASY
Which reaction is useful in exchange of halogen in alkyl chloride by iodide?
MEDIUM
Identify compound X in the following sequence of reactions
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EASY
The conversion of ethyl bromide to ethyl iodide using sodium and dry acetone, this reaction is known as
MEDIUM
Excess of isobutane on reaction with Br2 in presence of light at 125°C gives which one of the following, as the major product?
MEDIUM

The major product (Q) of the below reactions is

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HARD
The total number of monobromo derivatives formed by the alkanes with molecular formula C5H12 is (excluding stereo isomers)
EASY
The following reaction is known as
R-CH2Br+AgF ethyleneglycol ΔR-CH2 F+AgBr
MEDIUM

The major products, P and Q, formed in the reactions given below are:

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HARD
The product of the reaction give below is:

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EASY
The synthesis of alkyl fluorides is best accomplished by: