Systematic Analysis of Cationic Radicals

Author:Embibe Experts
JEE Main/Advanced
IMPORTANT

Important Questions on Systematic Analysis of Cationic Radicals

EASY
IMPORTANT

A gas is obtained by addition of dil. HCl to a mixture which turns lead acetate paper black. It is

HARD
IMPORTANT

For the given aqueous reactions, which of the statement(s) is (are) true?
Question Image

MEDIUM
IMPORTANT

Upon treatment with ammoniacal H2S, the metal ion that precipitates as a sulfide is

MEDIUM
IMPORTANT

Which pair of compounds is expected to show similar colour in aqueous medium?

HARD
IMPORTANT

Which of the following compound will not turn black on adding NH4OH to it?

MEDIUM
IMPORTANT

Out of the following X is number of salt which have yellow or orange colour precipitates. Then value of x2 is
CdS, ZnS, As2S3, As2S5, CoS, BaCO3, PbS, CuCN2, Agl, PbI2

HARD
IMPORTANT

Solution of following cations is treated with excess of NaOH, the number of diamagnetic cations which form soluble complex is x.
Pb2+, Sn2+, Al3+, Fe2+, Zn2+, Mn2+, Cr3+, Ni2+
The value of 3x will be

HARD
IMPORTANT

0.33M solution of aluminium chloride AlCl3 is used for the quantitative analysis of Al+3 ions. If NaOH is added in 0.33 M AlCl3 a while ppt is formed and when excess NaOH is added it dissolved by forming soluble tetrahydroxoaluminate ion Al(OH)4-, if NH4+ ions are added to Al(OH)4-, then

HARD
IMPORTANT

Tin (II) ion is used in identification of mercury (I) or mercury (II) ion in the qualitative analysis of basic radical. Select the correct statement about this experiment.
Experiment : Hg+2+Sn2+

HARD
IMPORTANT

The number of intramolecular hydrogen bondings in Ni(DMG)2 complex

HARD
IMPORTANT

An aqueous solution of a mixture of two inorganic salts. When treated with dilute HCl gave a precipitate of (P) and a filtrate (Q). The precipitate (P) was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H2S in a dilute mineral acid medium. However, it gave a precipitate (R) with ammonium chloride and ammonium hydroxide. The precipitate (R) gave a coloured solution (S) When treated with H2O2 in an aqueous NaOH. The cation in precipitate (P) and coloured solution (S) contains respectively

HARD
IMPORTANT

The sulphides of some metal given in List I and their Ksp  value is given in List II. What will be the correct option

  List-I   List-II
I CuS p 1.6×10-54
II CaS q 2.5×10-23
III HgS r 8×10-37
IV ZnS s 8×10-6

 

HARD
IMPORTANT

Generally chromium (III) is identified after oxidation to chromate ion. The oxidising agent that can be used for this oxidation is

MEDIUM
IMPORTANT

Which of the following statements is not correct with reference to Cu+2 and Cd+2 ?