Elevation of Boiling Point

IMPORTANT

Elevation of Boiling Point: Overview

This topic covers concepts such as boiling point, elevation of boiling point and molal boiling point elevation constant using molar heat of vapourisation.

Important Questions on Elevation of Boiling Point

MEDIUM
IMPORTANT

A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.86°C,  whereas, pure ether boils at 35.60°C.

The molecular mass of the solute would be: (for etherKb=2.05Kkgmol1)

MEDIUM
IMPORTANT

If an equimolar solution of CaCl2, and AlCl3 in water have boiling point of T1 and T2 respectively then

HARD
IMPORTANT

If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2: 1 and their enthalpy of vaporizations are in the ratio 1: 2, then the boiling point elevation constant of X is m times the boiling point elevation constant of Y. The value of m is (nearest integer).

MEDIUM
IMPORTANT

The vapour pressure vs. temperature curve for a solution solvent system is shown below.

Question Image

 

The boiling point of the solvent is _____°C.

HARD
IMPORTANT

Calculate the elevation in boiling point of an aqueous solution of 0.1 molal monobasic acid, which undergoes 25% ionization is (Kb(H2O)=0.52 Kmolal-1)

MEDIUM
IMPORTANT

Calculate the molal elevation boiling point constant of a solution containing 1.0 g of urea (M=60) in 75 g water and boils at 100.114C.

MEDIUM
IMPORTANT

The molal elevation constant for water is 0.56 K kg mol1. Calculate the boiling point of solution made by dissolving 6.0 g of urea (NH2CONH2) in 200 g of water.

EASY
IMPORTANT

The rise in boiling point of a solution containing 1.8 g of glucose in 100 g of solvent is 0.1°C. The molal elevation constant of the liquid is

EASY
IMPORTANT

The aqueous solution that shows the maximum boiling point elevation is [Assume identical conditions]

HARD
IMPORTANT

Calculate the boiling point of solution when 4 g of MgSO4 M=120 g mol-1 was dissolved in 100 g of water, assuming MgSO4 undergoes complete ionization. (kb for water=0.52 K Kg mol-1)

HARD
IMPORTANT

6 g of urea and 1 g of glucose are dissolved 300 g of water find the boiling point of solutions and pure water boiling point is 100Ckb for water is 0.52 kkg/mol.

MEDIUM
IMPORTANT

A student observed that the boiling of the water containing 10 g/l of NaCl was 101.5C. If more water is added to the solution, will its boiling point increase or decrease? Give reason.

HARD
IMPORTANT

1L of aq. Solution of urea having density = 1.060 gm/mL is found to have ΔTb = 0.5°C, if temperature of this solution increase to 101.5°C then calculate amount of water which must have gone into vapour state up to this point. Given Kb= 0.5 Kkgmol-1 for water

MEDIUM
IMPORTANT

Which of the following aqueous solutions should have the minimum boiling point?

EASY
IMPORTANT

Two liquids A and B boil at 145° C and 190° C respectively. Which of them has a higher vapour pressure at 80° C?

EASY
IMPORTANT

Why boiling point of water is increased on the addition of sodium chloride into it?

EASY
IMPORTANT

What will happen to the boiling point of a solution if the weight of the solute dissolved is doubled but the weight of solvent taken is halved?

EASY
IMPORTANT

Which solution has maximum boiling point?

HARD
IMPORTANT

68.4 g of sugar (molecular weight = 342 g) is dissolved in 1000 g of water. What is the boiling point of solution? The density of the solution at 20°C is 1.024 g cm-3. The vapour pressure of water at 20°C is 17.633 mm. The Kf and Kb values , for water are 1.873°C and 0.516°C respectively.

EASY
IMPORTANT

Define molal elevation constant or ebullioscopic constant.