Thermodynamics
Chemistry Solutions from Chapter -1 - Thermodynamics
This chapter focuses on thermodynamics with its related applications. We will also learn the use of calorimeter and enthalpy change. Further, it includes the explanation of enthalpies for different types of reactions and spontaneity.
Practice Other Topics from Thermodynamics
In this topic, we will discuss the system and the surroundings, open system, close system, isolated system, state of the system and internal energy as state function in detail.

In this topic, we will learn the first law of thermodynamics. It also gives us an introduction and properties of this law. The concept of initial to final states is also explained here with the help of equations.

In this topic, we shall study the pressure-volume work, PV plot based on various conditions. It also explains isothermal and free expansion of ideal gas, reversible and irreversible conditions and processes in detail.

This topic highlights a useful new state function. We will also study the various types of reactions for negative and positive change in enthalpies. It also deals with extensive and intensive properties and heat capacities in detail.

In this topic, we will learn technique of measurement of energy changes associated with chemical and physical processes called calorimetry. It explains the technique with the help of experiments and diagrams.

This topic highlights the concept of reaction enthalpy, standard enthalpy of reactions, change in enthalpy during phase transformation. It also explains standard enthalpy of formation, thermochemical equation and Hess's law of constant heat summation.

In this topic, we will study meaning of the Hess's law of constant heat summation in detail. We will also learn the importance of this law with the help of a brief example.

In this topic, we will study the detailed explanation of standard enthalpy of combustion and enthalpy of atomization. It also explains bond enthalpy, lattice enthalpy, enthalpy of solution and enthalpy of dilution.

In this topic, we will understand spontaneity. It explains the criteria of spontaneity and relation between entropy and Gibbs free energy to the spontaneity. We will also learn about the connection between entropy and second law and third law of thermodynamics.

In this topic, we will learn increase in entropy for an isolated system and the explanation of the commonness of spontaneous exothermic reactions through the second law of thermodynamics.

In this topic, we will learn to predict the spontaneity of the chemical reaction through Gibbs energy. We will also understand to predict the amount of work that could be extracted from it.
