Reactions of Amines

IMPORTANT

Reactions of Amines: Overview

This topic covers concepts such as basic strength of aliphatic amine, basic strength of aliphatic amine in polar protic solvent, chemical properties of amines, basic character of amines, and alkylation of amines.

Important Questions on Reactions of Amines

MEDIUM
IMPORTANT

State which of the following statements are true:

(i)   p K b value for aniline is less than that for methylamine.

(ii) Methylamine in water reacts with ferric chloride to give a precipitate of ferric hydroxide.

(iii) Aniline does not undergo Friedel-Crafts reaction.

EASY
IMPORTANT

 The order of basic strength in gas phase of the following compound would be:

  i) C 2 H 5 NH 2 , ii) (C 2 H 5 ) 2 NH, iii) (C 2 H 5 ) 3 Nand iv) CH 3 NH 2 .

MEDIUM
IMPORTANT

Compound A from the following reaction sequence is :

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HARD
IMPORTANT

The incorrect statement regarding the reaction given below is

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EASY
IMPORTANT

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Compare basic strength of a,b,c:

MEDIUM
IMPORTANT

Arrange the following in decreasing order of their pKb values

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HARD
IMPORTANT

Among methanamine, ethanamine, benzenamine, N-methylaniline and N, N-dimethylaniline, the weakest and the strongest base in aqueous phase, respectively are

HARD
IMPORTANT

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MEDIUM
IMPORTANT

Which is the correct basic strength order of the following compounds?

i)

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ii)

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iii)

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iv)

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HARD
IMPORTANT

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A and B are

HARD
IMPORTANT

In the following reaction sequence,

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What are the compound X and Z.

EASY
IMPORTANT

O-methylbenzylamine gives positive carbylamine test.

MEDIUM
IMPORTANT

The decreasing order of basicity of following aniline derivatives is:

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HARD
IMPORTANT

CH3COOHNH3A Br2+KOH B CHCl3+NaOH C

The number of carbons present in the product C is

EASY
IMPORTANT

The CORRECT order of basic strength of following compounds is

HARD
IMPORTANT

Ph-NC is prepared by

MEDIUM
IMPORTANT

Arrange the following compounds in order of decreasing basicity.

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MEDIUM
IMPORTANT

Select the correct order of basicity for the following compounds.

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MEDIUM
IMPORTANT

An organic amino compound reacts with aqueous nitrous acid at low temperature to produce an oily nitrosoamine. The compound is:

EASY
IMPORTANT

Which of the following compounds goes to aqueous layer while extracting the mixture containing the four compounds with 1M HCl?
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