Reactions of Diazonium Salts

IMPORTANT

Reactions of Diazonium Salts: Overview

This Topic covers sub-topics such as Sandmeyer's Reactions, Balz-Schiemann Reaction, Hydrolysis of Diazonium Salts, Chemical Reactions of Diazonium Salts, Reaction of Diazonium Salts with Ethanol or H3PO2 and, Diazo Coupling Reactions of Diazonium Salts

Important Questions on Reactions of Diazonium Salts

MEDIUM
IMPORTANT

The products of the following reactions are

(i)  C6H5N2Cl+Cu2Cl2

(ii)  C6H5NH2+Br2(aq)

MEDIUM
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The reaction that occurs when iodide ions replace diazonium group from a diazonium salt is known as:

EASY
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The reaction that occurs when iodide ions replace diazonium group from a diazonium salt is known as:

MEDIUM
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Identify the product in the following reaction

Question Image

MEDIUM
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Consider the following sequence of reactions

Question Image

The product ‘B’ is

 

HARD
IMPORTANT

Isomeric amines with molecular formula C8H11N give the following tests

IsomerP Can be prepared by Gabriel phthalimide synthesis

IsomerQ Reacts with Hinsberg’s reagent to give solid insoluble in NaOH

IsomerR Reacts with HONO followed by β-naphthol in NaOH to give red dye.

IsomersP, Q and R respectively are

HARD
IMPORTANT

Match List I with List II :

Question Image s reacted with reagents in List I to form products in List II

products in List II.

List I (Reagent)                                                       List II (Product)
A. Question Image I. Question Image
B. HBF4,Δ II. Question Image
C. Cu, HCl III. Question Image
D. CuCN/KCN IV. Question Image
Choose the correct answer from the options given below:

 

HARD
IMPORTANT

Complete the following chemical equations :

C6H5N2Cl+C6H5OHOH-

HARD
IMPORTANT

Complete the following chemical equations :

C6H5N2Cl+C6H5NH2OH-

MEDIUM
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What is Sandmayer's reaction. Explain.

HARD
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Question Image

The product (B) is

EASY
IMPORTANT

Explain the conversion of benzene diazonium fluoroborate to fluorobenzene.

EASY
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Explain balz-Schiemann reaction with equation.

EASY
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Reaction of C6H5N2Cl with aniline in basic medium produces

EASY
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Example for antidepressant drug

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Which of the following molecule does not involve in a coupling reaction with benzene diazonium chloride?

MEDIUM
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Phenol on reaction with benzenediazonium chloride forms orange dye.

MEDIUM
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Which of the following the product is formed by the reaction of phenol with benzenediazonium chloride?

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Define coupling reaction. Give an example.

MEDIUM
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When benzene diazonium chloride is heated with ethyl alcohol it gives benzyl alcohol and ethanal.