Chemical Properties of Aldehydes And Ketones
Chemical Properties of Aldehydes And Ketones: Overview
This Topic covers sub-topics such as Cannizzaro's Reaction, Aldol Condensation, Perkin's Reaction, Cross-Aldol Condensation, Haloform Reaction, Benzoin Condensation, Mechanism of Aldol Condensation, Claisen-Schmidt Reaction and, Knoevenagel Reaction
Important Questions on Chemical Properties of Aldehydes And Ketones
The reaction of cyclopentanone with diazomethane gives
Complete the following reaction:
Two molecules of benzaldehyde undergo condensation in the presence of a cyanide catalyst (e.g., or ) to form -hydroxy--diphenylethanone.
Give the IUPAC name of the compound formed when two molecules of benzaldehyde undergo condensation in the presence of a cyanide catalyst (e.g., or ).
Explain Benzoin condensation reaction.
-pentanone on oxidation with alkaline gives methanoic acid and butanoic acid.
Which of the following acid(s) is/are not formed on the reaction of -pentanone with alkaline ?
The reaction of -pentanone with alkaline gives
Write equation for the reaction of -pentanone with alkaline .
State popoff's rule.
Tatrazine dye is formed on condensation of benzaldehyde with N, N – dimethyl aniline in the presence of strong acid.
Benzaldehyde on reaction with N, N – dimethyl aniline in the presence of strong acid forms
Name the product formed in the given reaction:
Explain the condensation of benzaldehyde with tertiary aromatic amines.
_____ condensation reaction is a nucleophilic addition between an aldehyde or ketone, and an active hydrogen compound in the presence of a basic catalyst, resulting in a bond formation usually followed by spontaneous dehydration resulting in an unsaturated product.
Acetone reacts with malonic acid in presence of pyridine followed by dehydration to give
Write the general equation for Knoevenagel reaction.
Explain Knoevenagel reaction.
Write the mechanism for aldol condensation.
How does carbonyl compounds react with diazomethane?