Chemical Reactions of Haloarenes

Benzyl chloride  $\left(C_6{H}_{5}C{H}_{2}Cl\right)$ can be prepared from toluene by chlorination with –

The structure of the major organic product expected form the following reaction are

${\mathrm{C}}_6{\mathrm{H}}_{6 }\text{(Benzene)}+{\left({\mathrm{CH}}_3\right)}_2{\mathrm{CHCH}}_2\mathrm{Cl}\stackrel{{\mathrm{AlCl}}_3}{\to }$

In the following reaction, the nucleophile $(Me{O}^{⊝} )$ will displace which of the halogen atoms most readily?

Examine the structural formula shown below and find out how many compounds undergo electrophilic nitration more rapidly than fluoro benzene.

Assertion: In mono haloarenes, electrophilic substitution occurs at ortho and para positions.

Reason: Halogen atom is a ring deactivator.
 

The metal used in the Ullmann reaction is

Why does benzene undergo an electrophilic substitution reaction easily?

Explain electrophilic substitution reaction in haloarenes.

Which of the following statements are correct?

$\left(\mathrm{ii}\right)$  Resonance effect dominates over inductive effect in Anisole
$\left(\mathrm{iii}\right) \mathrm{P}-$nitrobenzoic acid is less acidic than $\mathrm{m}$-nitrobenzoic acid
$\left(\mathrm{iv}\right)$ Diphenylamine is more basic than aniline

 Electrophilic substitution reactions of Haloarenes are

 Electrophilic substitution reactions of Haloarenes are

Write the mechanism of the electrophilic substitution reaction of Haloarenes.

Arrange the following compounds in incrensing order of their rate of reaction towards hydroxyl ion $\left({\mathrm{OH}}^{-}\right)$.

I 

II

III 

IV 

The halogen compound which will not react with phenol to give ethers is

The halogen compound which will not react with phenol to give ethers is

The rates of reaction of $\mathrm{NaOH}$ with:

follow the order:-

In the questions arrange the compounds in increasing order of rate of reaction towards nucleophilic substitution.

Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to:

Which of the following reaction gives ethane?