Solubility and Equilibria of Sparingly Soluble Salts

IMPORTANT

Solubility and Equilibria of Sparingly Soluble Salts: Overview

This Topic covers sub-topics such as Solubility Product, Relation between Solubility and Solubility Product, Insoluble Salts, Applications of Solubility Product, Solubility Equilibria of Sparingly Soluble Salts and, Purification of Common Salt

Important Questions on Solubility and Equilibria of Sparingly Soluble Salts

MEDIUM
IMPORTANT

The solubility product of a salt having general formula   MX 2 , in water is   4× 10 12 .  The concentration of  M2+ ions in the aqueous solution of the salt is –

MEDIUM
IMPORTANT

Solubility products of CuI and Ag2CrO4 have almost the same value ~4×10-12. The ratio of solubilities of the two salts CuI:Ag2CrO4 is closest to 

EASY
IMPORTANT

The solubility of BaSO4 in pure water (in gL-1 ) is closest to
Given; Ksp for BaSO4 is 1.0×10-10 at 25°C. Molecular weight of BaSO4 is 233 g mol-1 ]

EASY
IMPORTANT

If the solubility of a M2S salt is 3.6×10-5, find its solubility product.

EASY
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By which of the following processes can the common salt be purified?

EASY
IMPORTANT

Which acid is used in the purification of common salt?

HARD
IMPORTANT

A saturated solution of CaSO4 is prepared at 25°C. When 200 mL of this solution is allowed to complete evaporation of water, 0.34 g of residue obtained. The Ksp of CaSO4 at 25°C will be:

MEDIUM
IMPORTANT

pH of a saturated solution of BaOH2 is 12. Hence, Ksp of BaOH2

MEDIUM
IMPORTANT

Solubility of thorium phosphate (molar mass =m) is wg/100 mL at 25°C. The Ksp of thorium phosphate is :

HARD
IMPORTANT

The Ksp of Ag2CrO4 is 1.1×10-12 at 298 K. The solubility (in mol L-1) of Ag2CrO4 in a 0.1 M AgNO3 solution is :

MEDIUM
IMPORTANT

The solubility of AgCls with solubility product 1.6×10-10 in 0.1 M NaCl solution would be :

MEDIUM
IMPORTANT

Calculate the molar solubility of AgCl at 25°C in 3.0MNH3

Ksp of AgCl=2.0×10-10, Kf of AgNH32+=1.25×107)
 

MEDIUM
IMPORTANT

If solubility of sparingly soluble compound MOH3 in a solution of pH=12 is x×10y then calculate y. Solubility of MOH3 in pure water is 2×107.

HARD
IMPORTANT

If 10-x is the factor by which solubility of AgBr(s) Ksp=10-10 changes with respect to initial solubility, when it is dissolved in 0.01M NaBr (aq) solution. The value of X'' is :

HARD
IMPORTANT

Calculate the solubility of silver phosphate Ag3PO4 in 0.1MAgNO3 Ksp of Ag3PO4=1.1×10-16):-

MEDIUM
IMPORTANT

Calculate the molar solubility of NiOH2 in 0.1 M NaOH. The solubility product of NiOH2 is 2×10-15. (Given: 0.53=0.79)

HARD
IMPORTANT

pH of a saturated solution of Ba(OH)2 is 12. Hence, Ksp of Ba(OH)2 is:

MEDIUM
IMPORTANT

At 25°C, the solubility product of Mg (OH)2is 1.0×10-11. At which pH, will Mg2+ ions start precipitating in the form of Mg(OH)2 from a solution of 0.001MMg2+ ions ? 

EASY
IMPORTANT

What is the minimum concentration of SO42- required to precipitate BaSO4 in a solution containing 1×10-4 mole of Ba2+ ? Ksp for BaSO4=4×10-10

HARD
IMPORTANT

The solubility of salt in saturated aqueous solution of NH4KHPO3 is :-