Applications of Thermodynamics: Enthalpy

IMPORTANT

Applications of Thermodynamics: Enthalpy: Overview

This topic consists of various concepts like Enthalpy,Molar Heat Capacity at Constant Pressure (Cp),Relationship Between Cp and Cv for an Ideal Gas, etc.

Important Questions on Applications of Thermodynamics: Enthalpy

HARD
IMPORTANT

For the reaction :

C3H8g+5O2g3CO2g+3H2Ol

H-U at constant temperature is 

MEDIUM
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When a 60 W electric heater is immersed in a gas for 100 s in a constant volume container with adiabatic walls, the temperature of the gas rises by 5°C. The heat capacity of the given gas is JK-1 (Nearest integer)

HARD
IMPORTANT

Change in internal energy of an ideal gas is given byU=nCvT. Explain?

HARD
IMPORTANT

Heat of reaction for, C6H12O6s+6O2g6CO2g+6H2Ov at constant pressure is -651 kcal at 17°C. Calculate the heat of reaction at constant volume at 17°C.

HARD
IMPORTANT

Among the following standard enthalpy of formation is non-zero for

HARD
IMPORTANT

2 mol of Hg(g) is combusted in a fixed volume bomb calorimeter with excess of O2 at 298 K and 1 atm into HgO(s). During the reaction, temperature increases from 298.0 K to 312.8 K. If heat capacity of the bomb calorimeter and enthalpy of formation of Hg(g) are 20.00 kJ K-1 and 61.32 kJ mol-1 at 298 K, respectively, the calculated standard molar enthalpy of formation of HgO(s) at 298 K is X kJ mol-1. The value of|X| is ____. [Given: Gas constant R = 8.3 J K-1 mol-1]

EASY
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What is enthalpy?

MEDIUM
IMPORTANT

A 150 W heater was placed in 1.00 kg of methanol(CH3OH) and turned on for exactly for 1 min. The temperature increased by 3.54 K. Assuming that all the heat is absorbed by methanol, the molar heat capacity of methanol is 

MEDIUM
IMPORTANT

The difference between the value of Cp of H2 and Cv of He will be :

MEDIUM
IMPORTANT

Which statement is correct?

HARD
IMPORTANT

The density of a substance is 400kgm3 and that of another substance is 600kgm3 . The heat capacity of 40c.c of first substance is equal to that of 30c.c of second substance. The ratio of their specific heats is

MEDIUM
IMPORTANT

Heat required to raise the temperature of 54 g of steam (H2O) by 5°C in a rigid and closed vessel is

MEDIUM
IMPORTANT

Which of the following has lowest specific heat value

MEDIUM
IMPORTANT

From the following data at constant volume for combustion of benzene, calculate the heat of this reaction at constant pressure condition.
C6H6l+712O2g6CO2g+3H2O(l),  ΔU at U=-3268.12 kJ.

MEDIUM
IMPORTANT

5 moles of an ideal monoatomic gas undergoes adiabatic expansion from 5 L to 20 L against a constant external pressure of 2 bar.

HARD
IMPORTANT

One mole ideal monoatomic gas is heated according to path AB and AC. If temperature of state B and state C are equal.
Calculate qACqAB×10.

Question Image

Round off your to the nearest integer.

EASY
IMPORTANT

A monoatomic ideal gas kept in a vessel fitted with a piston is expanded irreversibly from its initial state (1L,1atm, at 300K) to the final state (10L,420K). The enthalpy and entropy changes in the process are, respectively

HARD
IMPORTANT

Value of γ for CH4 molecule is (Consider vibrational degree of freedom to be active)

MEDIUM
IMPORTANT

When equal volumes of Helium and Neon at same temperature and pressure are mixed, the ratio Cp:Cv of the mixture equals: